For a general reaction A  B, the plot of the concentration of A vs. time is given in the figure.
 

The slope of the curve will be:

1. -k 2. -k/2
3. -k2 4. -k/3

Subtopic:  Definition, Rate Constant, Rate Law |
 89%
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A first-order reaction takes 40 min for 30 % decomposition. The half life of the reaction will be: 

1. 88.8 min 2. 94.3 min
3. 67.2 min 4. 77.7 min

Subtopic:  First Order Reaction Kinetics |
 61%
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The rate constant for the decomposition of hydrocarbons is 2.418 × 10–5 s–1 at 546 K. If the energy of activation is 179.9 kJ/mol, the value of the pre-exponential factor will be:

1. 4.0 × 1012 s-1
2. 7.8 × 10-13 s-1
3. 3.8 × 10-12 s-1
4. 4.7 × 1012 s-1

Subtopic:  Arrhenius Equation |
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For a reaction A  Product, with k = 2.0 × 10–2 s–1, if the initial concentration of A is 1.0 mol L-1, the concentration of A after 100 seconds would be :

1. 0.23 mol L-1 2. 0.18 mol L-1
3. 0.11 mol L-1 4. 0.13 mol L-1
Subtopic:  First Order Reaction Kinetics |
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The decomposition of sucrose follows the first-order rate law. For this decomposition, t1/2 is 3.00 hours. The fraction of a sample of sucrose that remains after 8 hours would be:

1. 0.13 2. 0.42
3. 0.16 4. 0.25
Subtopic:  First Order Reaction Kinetics |
 54%
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The decomposition of hydrocarbons follows the equation: k = (4.5 × 1011s–1) e-28000K/T

The activation energy (Ea) for the reaction would be:

1. 232.79 kJ mol-1 2. 245.86 kJ mol-1
3. 126.12 kJ mol-1 4. 242.51 kJ mol-1
Subtopic:  Arrhenius Equation |
 73%
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The rate constant for the first-order decomposition of H2O2 is given by the equation: \(log \ k \ = \ 14.34 \ - \ 1.25 \ \times \ 10^{4}\frac{K}{T}\)The value of Ea for the reaction would be:

1. 249.34 kJ mol-1

2. 242.64 J mol-1

3. -275.68 kJ mol-1

4. 239.34 kJ mol-1

Subtopic:  Arrhenius Equation |
 56%
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The reaction below is an example of:

CH3COOC2H5   +   H2O   \(\xrightarrow[]{H^{+}}\) CH3COOH  +   C2H2OH
Ethyl acetate                           Acetic acid     Ethyl alcohol



1. Pseudo-first-order reaction

2. First-order reaction

3. Second order reaction

4. Third-order reaction

Subtopic:  Order, Molecularity and Mechanism |
 87%
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The rate constant for a first-order reaction is 4.606×10-3 s-1. The time required to reduce 2.0 g of the reactant to 0.2 g will be:

1. 200 s 2. 500 s
3. 1000 s 4. 100 s
Subtopic:  First Order Reaction Kinetics |
 85%
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An increase in the concentration of the reactants of a reaction leads to a change in:

1. Heat of reaction 2. Threshold energy
3. Collision frequency 4. Activation energy
Subtopic:  Arrhenius Equation |
 69%
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