Which of the following pairs of ions are isoelectronic and isostructural?

1. ${\mathrm{CO}}_3^{2-}, {\mathrm{SO}}_3^{2-}$

2. ${\mathrm{ClO}}_3^{-}, {\mathrm{CO}}_3^{2-}$

3. ${\mathrm{SO}}_3^{2-}, {\mathrm{NO}}_3^{-}$

4. ${\mathrm{ClO}}_3^{-}, {\mathrm{SO}}_3^{2-}$

The correct order of \(\mathrm{C-O}\) bond length among \(\mathrm{CO},\mathrm{CO}_3^{2-},\) and \(\mathrm{CO_2}\) is :

1. \(\mathrm{CO}_2<\mathrm{CO}_3^{2-}<\mathrm{CO} \)
2. \(\mathrm{CO}<\mathrm{CO}_3^{2-}<\mathrm{CO}_2 \)
3. \(\mathrm{CO}_3^{2-}<\mathrm{CO}_2<\mathrm{CO} \)
4. \(\mathrm{CO}<\mathrm{CO}_2<\mathrm{CO}_3^{2-}\)

A molecule that has a complete octet is:

 1. BeCl₂(dimer)       

 2. BeH₂(dimer)

 3. BeH₂(s)               

 4. BeCl₂(s)

Mg₂C₃ reacts with water forming propyne ${\mathrm{C}}_3^{4-}$ . The number of sigma and pie bonds in \(C_{3}^{4-}\)is-  

1. Two sigma and two pi bonds.             

2. Three sigma and one pi bonds.           

3. Two sigma and one pi bonds.          

4. Two sigma and three pi bonds.

The maximum number of 90° angles between bond pair-bond pair of electrons is observed in:

1.  sp³d²-hybridization.            

2.  sp³d-hybridization.

3.  dsp²-hybridization.             

4.  dsp³-hybridization.

The molecule/s that will have non zero dipole moments is /are : 

1. 1,2-dichloro benzene.
2. Cis-3-hexene.
3. Trans-2-pentene.
4. All of the above.

Match the compounds given in Column I with the hybridization and shape given in Column II and mark the correct option. 

The correct geometry and hybridization for XeF₄ are : 

1.  Octahedral, sp³d²

2.  Trigonal bipyramidal, sp³d³

3.  Planar triangle, sp³d³

4.  Square planar, sp³d²

Which molecule is least likely to form hydrogen bonds? 

A molecule among the following with non-zero dipole moment is:

1. ${\mathrm{C}}_6{\mathrm{Cl}}_6$

2. ${\mathrm{C}}_2{\mathrm{Cl}}_6$

3. $\mathrm{C}{\left({\mathrm{CCl}}_3\right)}_4$

4. $:{\mathrm{CCl}}_2$