Given below are two statements:
Assertion (A): | Vinyl halides do not undergo nucleophilic substitution easily. |
Reason (R): | Even though the intermediate carbocation is stabilized by loosely held p-electrons, the cleavage is difficult because of strong bonding. |
1. | Both (A) and (R) are true and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are true but (R) is not the correct explanation of (A). |
3. | (A) is true but (R) is false. |
4. | Both (A) and (R) are false. |
Select the correct option based on statements below:
Assertion (A): | Hydrolysis of (-)-2-bromooctane proceeds with an inversion of configuration. |
Reason (R): | This reaction proceeds through the formation of a carbocation. |
1. | Both (A) and (R) are true and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are true but (R) is not the correct explanation of (A). |
3. | (A) is true but (R) is false. |
4. | (A) is false but (R) is true. |
Given below are two statements:
Assertion (A): | It is difficult to replace chlorine by -OH in chlorobenzene in comparison to that in chloroethane. |
Reason (R): | Chlorine carbon (C—Cl) bond in chlorobenzene has a partial double bond character due to resonance. |
1. | Both (A) and (R) are true and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are true but (R) is not the correct explanation of (A). |
3. | (A) is true but (R) is false. |
4. | (A) is false but (R) is true. |
Given below are two statements:
Assertion (A): | tert-butyl bromide undergoes Wurtz reaction to give 2,2,3,3-tetramethylbutane. |
Reason (R): | In Wurtz reaction, alkyl halides react with sodium in dry ether to give hydrocarbon containing double the number of carbon atoms present in the halide. |
1. | Both (A) and (R) are true and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are true but (R) is not the correct explanation of (A). |
3. | (A) is true but (R) is false. |
4. | (A) is false but (R) is true. |
Select the correct option based on statements below:
Assertion (A): | KCN reacts with methyl chloride to give methyl isocyanide. |
Reason (R): | \(CN^-\) is an ambident nucleophile. |
1. | Both (A) and (R) are true and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are true but (R) is not the correct explanation of (A). |
3. | (A) is true but (R) is false. |
4. | (A) is false but (R) is true. |
Select the correct option based on statements below:
Assertion (A): | Phosphorus chlorides (tri and Penta) are preferred over thionyl chloride for the preparation of alkyl chlorides from alcohols. |
Reason (R): | Phosphorus chlorides give pure alkyl halides. |
1. | Both (A) and (R) are true and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are true but (R) is not the correct explanation of (A). |
3. | (A) is true but (R) is false. |
4. | Both (A) and (R) are false. |
Select the correct option based on statements below:
Assertion (A): | Vinyl chloride can be easily hydrolyzed. |
Reason (R): | Resonance is not observed in vinyl chloride. |
1. | Both (A) and (R) are true and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are true but (R) is not the correct explanation of (A). |
3. | (A) is true but (R) is false. |
4. | Both (A) and (R) are false. |
Statement I: | Sulphuric acid not used during the reaction of alcohols with KI. |
Statement II: | H2SO4 is an oxidizing agent, it oxidizes HI produced in the reaction to I2 . |
1. Both Statement I and II are true.
2. Statement I is true and statement II is false.
3. Both Statement I and II are false.
4. Statement I is false, Statement II is true.
Ethylene chloride and ethylidene chloride are isomers. Identify the correct statements.
a. | Both the compounds form same product on treatment with alcoholic KOH |
b. | Both the compounds form same product on treatment with aq. NaOH |
c. | Both the compounds form same product on reduction |
d. | Both the compounds are optically active |
Choose the correct option
1. (a, b)
2. (b, c)
3. (c, d)
4. (a, c)
Which of the following statements is correct about the kinetics of the above-given reaction?
(i). | The rate of reaction depends on the concentration of only (b). |
(ii). | The rate of reaction depends on the concentration of both (a) and (b). |
(iii). | Molecularity of reaction is one. |
(iv). | Molecularity of reaction is two. |
Choose the correct option
1. (i, ii)
2. (ii, iii)
3. (iii, iv)
4. (i, iii)