In the electrochemical cell:

Zn|ZnSO₄(0.01 M) || CuSO₄(1.0M),Cu, the emf of this Daniel cell is E₁. When the concentration of ZnSO₄ is changed to 1.0 M and that of CuSO₄ is changed to 0.01 M, the emf changes to E₂. The relationship between E₁ and E₂ is : 
( Given, $\frac{RT}{\mathrm{F }}$= 0.059)

1. E₁ = E₂

2. E₁ < E₂

3. E₁ > E₂

4. E₂ = 0 $\ne$E₁

The molar conductivity of a solution of AgNO₃ (considering the given data for this solution) at 298 K is:
(a) Concentration: 0.5 mol/dm³
(b) Electrolytic conductivity: 5.76×10^–3 S cm^–1

During the electrolysis of molten sodium chloride, the time required to produce 0.10 mol of chlorine gas using a current of 3 amperes is

(1) 55 minutes                       

(2) 110 minutes

(3) 220 minutes                       

(4) 330 minutes

If the E°_cell for a given reaction has a negative value, which of the following gives correct relationships for the values of $∆$G° and K_eq ?

(1) $∆$G° >0;  K_eq< 1

(2) $∆$G° >0; K_eq>1

(3) $∆$G° < 0; K_eq> 1

(4) $∆$G° <0; K_eq< 1

The number of electrons delivered at the cathode during electrolysis by a current of 1 ampere in 60 seconds is (charge on electron = 1.60 x 10^-19 C)

1. 6 x 10²³

2. 6 x 10²⁰

3. 3.75 x 10²⁰

4. 7.48 x 10²³

Zinc can be coated on iron to produce galvanised iron but the reverse is not possible. It is because

(1) zinc is lighter than iron

(2) zinc has lower melting point than iron

(3) zinc has lower negative electrode potential than iron

(4) zinc has higher negative electrode potential than iron

The pressure of H₂ required to make the potential of H₂-electrode zero in pure water at

298 K is

1. 10^-12 atm

2. 10^-10 atm

3. 10^-4 atm

4. 10^-14 atm

A device that converts energy of the combustion of fuels like hydrogen and methane, directly

into electrical energy is known as:

1. Fuel cell

2. Electrolytic cell

3. Dynamo

4. Ni-Cd cell

The weight of silver (atomic weight = 108) displaced by a quantity of electricity which displaces 5600 mL of O₂ at STP will be : 

1. 5.4 g

2. 10.8 g

3. 54.0 g

4. 108.0 g

At 25° C molar conductance of 0.1 molar aqueous solution of ammonium hydroxide is

9.54 ohm¹cm²mol^-1 and at infinite dilution its molar conductance is 238 ohm¹cm²mol^-1.

The degree of ionisation of ammonium hydroxide at the same concentration and

temperature is

1. 2.080%

2. 20.800%

3. 4.008%

4. 40.800%