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KMnO4 can be prepared from K2MnO4 as per reaction,

 3MnO42-+2H2O2MnO4-+MnO2+4OH-

The reaction can go to completion by removing OH- ions by adding             

1. HCl

2. KOH

3. CO2

4. SO2

Subtopic:  Introduction To Equilibrium |
Level 3: 35%-60%
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What can be the active mass of 5.6 L \(O_2\) gas at NTP ?

1.  0.25 Mol/L

2.  \({1 \over 22.4 } Mol /L\)

3. 0.175 Mol/L

4.  \({ 1 \over 5.6}~ Mol / L\)
Subtopic:  Introduction To Equilibrium |
Level 3: 35%-60%
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10 gm CaCO3 is taken in a one litre container. The active mass of CaCO3 is: 

1. 0.1

2. 1

3. zero

4. 10

Subtopic:  Introduction To Equilibrium |
Level 3: 35%-60%
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Assertion (A):  For the reaction:  H2(g) + I2(g)  \(\rightleftharpoons\)  2HI(g),  if the volume of the vessel is reduced to half of its original volume, the equilibrium concentration of all gases will be doubled.
Reason (R):  According to Le-Chatelier's principle, reaction shifts in a direction that tends to minimize the effect of stress.
 
1.  Both (A) and (R) are True and (R) is the correct explanation of (A).
2. Both (A) and (R) are True but (R) is not the correct explanation of (A).
3. (A) is True but (R) is False.
4. (A) is False but (R) is True.
Subtopic:  Le Chatelier's principle |
Level 3: 35%-60%
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What can be the active mass of CaCO3 if 10 grams of CaCO3 are taken in a one-liter container?
[Given: Molecular weight of CaCO3 = 100]

1. 0.1 

2. 1 

3. 0.01 

4. 10

Subtopic:  Le Chatelier's principle |
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Level 3: 35%-60%
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Given below are two statements:
Assertion (A): For every chemical reaction at equilibrium, standard Gibbs energy of the reaction is zero.
Reason (R): At constant temperature and pressure, chemical reactions are spontaneous in the direction of decreasing Gibbs energy.
 
1. Both (A) and (R) are True and (R) is the correct explanation of (A).
2. Both (A) and (R) are True but (R) is not the correct explanation of (A).
3. (A) is True but (R) is False.
4. (A) is False but (R) is True.
Subtopic:  Kp, Kc & Factors Affecting them |
Level 3: 35%-60%
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The equilibrium constant of the reaction A2(g) + B2(g)  2AB (g) at 100ºC is 50.  If a one litre flask containing one mole of A2 is connected to a two litre flask containing two moles of B2, how many moles of AB will be formed at 373 K ?

1. 2.8

2. 1.9

3. 2.1

4. 3.6

Subtopic:  Kp, Kc & Factors Affecting them |
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The increasing order of basic strength of Cl-CO32-, CH3COO-, OH-, F- is:

1. Cl-<F-<CH3COO-<CO32-<OH-

2.  Cl-<F-CO32-<CH3COO-<OH-

3. CH3COO-<Cl-<F-<CO32-<OH-

4. none of the above

Subtopic:  Acids & Bases - Definitions & Classification |
Level 3: 35%-60%
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Which of the following compounds are in the correct sequence in terms of relative basic strength?

1. \(C_{2} H_{5} O^{-} > CH \equiv C^{-} > \left(OH\right)^{-}\)

2. \(CH \equiv C^{-} >(OH)^{-} > C_{2} H_{5} O^{-}\)

3. \(CH \equiv C^{-} > C_{2} H_{5} O^{-} > \left(OH\right)^{-}\)

4. \(C_{2} H_{5} O^{-} > \left(OH\right)^{-} > CH \equiv C^{-}\)

Subtopic:  Acids & Bases - Definitions & Classification |
Level 3: 35%-60%
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Among the following examples, the species that behave(s) as a Lewis acid is/are: 
\(\mathrm{BF}_3, \mathrm{SnCl}_2, \mathrm{SnCl}_4\)

1. Stannous chloride, Stannic chloride
2. BF3, Stannous chloride
3. Only BF3
4. BF3, Stannous chloride, Stannic chloride

Subtopic:  Acids & Bases - Definitions & Classification |
Level 3: 35%-60%
AIPMT - 1999
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