Using equipartition of energy, the specific heat (in \(\text{J kg}^{-1}\text{K}^{-1}\) ) of aluminum at room temperature can be estimated to be:
(atomic weight of aluminum=27)
1. \(410\)
2. \(25\)
3. \(1850\)
4. \(925\)
Subtopic:  Law of Equipartition of Energy |
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Two moles of helium are mixed with \(n\) moles of hydrogen. If \(\frac{c_p}{c_v}=\frac{3}{2}\) for the mixture then, the value of \(n\) is:
1. \(1\)
2. \(3\)
3. \(2\)
4. \(\dfrac{3}{2}\)
Subtopic:  Law of Equipartition of Energy |
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An HCl molecule has rotational, translational and vibrational motions. If the rms velocity of HCl molecules in its gaseous phase is \(\vec{v}\), \(m\) is its mass and \(k_B\) is Boltzmann constant, then its temperature will be:
1. \( \frac{m v^{2}}{7 k_B} \)
2. \(\frac{m v^2}{6 k_B} \)
3. \(\frac{m {v}^2}{5 k_B} \)
4. \(\frac{m v^2}{3 k_B} \)
 

Subtopic:  Law of Equipartition of Energy |
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A gas mixture consists of \(3\) moles of oxygen and \(5\) moles of argon at temperature \(T.\) Assuming the gases to be ideal and the oxygen bond to be rigid, the total internal energy (in units of \(RT\)) of the mixture is:
1. \(11\)
2. \(15\)
3. \(20\)
4. \(13\)

Subtopic:  Law of Equipartition of Energy |
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Consider a gas of triatomic molecules. The molecules are assumed to be triangular, composed of massless rigid rods with atoms at the vertices. The internal energy of a mole of the gas at temperature \(T\) is:

               

1. \( 3 R T \) 2. \(\dfrac{5}{2} R T \)
3. \( \dfrac{9}{2} R T \) 4. \( \dfrac{3}{2} R T \)
Subtopic:  Law of Equipartition of Energy |
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To raise the temperature of a certain mass of gas by \(50^\circ\text{C}\) at a constant pressure, \(160\) calories of heat is required. When the same mass of gas is cooled by \(100^\circ\text{C}\) at constant volume, \(240\) calories of heat is released. How many degrees of freedom does each molecule of this gas have (assume the gas to be ideal)?
1. \(2\)
2. \(5\)
3. \(6\)
4. \(3\)

Subtopic:  Law of Equipartition of Energy |
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Match the \(C_p/C_V\)  ratio for ideal gases with different type of molecules :
 

Column I Column II
(A) Monatomic (I) \(7/5\)
(B) Diatomic rigid molecules (II) \(9/7\)
(C) Diatomic non-rigid molecules (III) \(4/3\)
(D) Triatomic rigid molecules (IV) \(5/3\)
 
1. (A)-(III), (B)-(IV), (C)-(II), (D)-(I)
2. (A)-(II), (B)-(III), (C)-( I), (D)-(IV)
3. (A)-(IV), (B)-(II), (C)-(I), (D)-(III)
4. (A)-(IV), (B)-(I), (C)-(II), (D)-(III)
 

Subtopic:  Law of Equipartition of Energy |
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Molecules of an ideal gas are known to have three translational degrees of freedom and two rotational degrees of freedom. The gas is maintained at a temperature of \(T.\) The total internal energy, \(U\) of a mole of this gas, and the value of \(\gamma~\left(=\dfrac{C_P}{C_V}\right )\) are, respectively:
1. \( U=5 R T \text { and } \gamma=\dfrac{7}{5} \)

2. \( U=\dfrac{5}{2} R T \text { and } \gamma=\dfrac{6}{5} \)

3. \(U=5 R T \text { and } \gamma=\dfrac{6}{5} \)

4. \( U=\dfrac{5}{2} R T \text { and } \gamma=\dfrac{7}{5}\)

Subtopic:  Law of Equipartition of Energy |
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The internal energy (\(U\)), pressure (\(P\)), and volume (\(V\)) of an ideal gas are related as \(U=3PV+4\). The gas is:

1. Diatomic only
2. Polyatomic only
3. Either monoatomic or diatomic
4. Monoatomic only

Subtopic:  Law of Equipartition of Energy |
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The ratio of specific heats \(\left (\dfrac{C_p}{C_v}\right)\) in terms of degree of freedom \((f)\) is given by:
1. \(\left(1+\dfrac{f}{3}\right) \) 2. \(\left(1+\dfrac{2}{f}\right)\)
3. \(\left(1+\dfrac{f}{2}\right) \) 4. \(\left(1+\dfrac{1}{f}\right)\)
Subtopic:  Law of Equipartition of Energy |
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