The IUPAC name of [\(\mathrm {C r \left(en\right)_{3}}\)]\(\mathrm{C l}_{3}\) is:

1. Triethylenediaminechromium (III) chloride
2. Tris(ethylenediammine)chromium (II) chloride
3. Tris(ethylenediammine)chromium (III) chloride
4. Tris(ethylenediamine)chromium (II) chloride

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The crystal field stabilization energy (CFSE) for [CoCl6]4- is 18000 cm-1.
The CFSE for [CoCl4]2-  will be:

1. 6000 cm-1

2. 16000 cm-1

3. 18000 cm-1

4. 8000 cm-1

Subtopic:  VBT, CFT & their Limitations |
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The electronic configuration that represents the maximum magnetic moment is:

1. d3

2. d2

3. d8

4. d6(high spin)

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Spin-only magnetic moments of [Fe(NH3)6]3+ and [FeF6]3-  in BM are, respectively :

1. 1.73 and 1.73 2. 5.92 and 1.73
3. 1.73 and 5.92 4. 5.92 and 5.92
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2.335 g of compound X (empirical formal CoH12N4Cl3) upon treatment with excess AgNO3 solution produces 1.435 g of a white precipitate. The primary and secondary valences of cobalt in compound X, respectively are:

[Given Atomic mass: Co = 59, Cl = 35.5, Ag = 108]

1. 3, 6 2. 3, 4
3. 2, 4 4. 4, 3
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The expected number of unpaired electrons for the complex ion [Cr(NH3)6]3+ are: 

1. 2

2. 3

3. 4

4. 5

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The complex that contains only one unpaired electron is:

1. [CoF6]3-

2. [Co(C2O4)3]3-

3. [Fe(CN)6]3-

4. [MnCl6]3-

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The complex that can exhibit linkage isomerism is:

1. [Co(NH3)5H2O]Cl3 2. [Co(NH3)5(NO2)]Cl2
3. [Co(NH3)5NO3](NO3)2 4. [CO(NH3)5Cl]SO4
Subtopic:  Isomerism in Coordination Compounds |
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The low spin complex among the following is:

1. \(\mathrm{Fe}(\mathrm{CN})_6^{3-} \) 2. \(\mathrm{Co}\left(\mathrm{NO}_2\right)_6^{3-} \)
3. \(\mathrm{Mn}(\mathrm{CN})_6^{3-} \) 4. All of the above
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For a tetrahedral complex [MCl4]2-, the spin-only magnetic moment is 3.83 B.M. The element M is:

1. Co

2. Cu

3. Mn

4. Fe

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