The reaction(s) involved in the preparation of potassium dichromate from iron chromite ore is/are:

1. FeCr2O+ NaOH + O→ Na2CrO4 + Fe2O3 + H2O
2. Na2CrO+ H2SO4 (conc.) →
Na2Cr2O+ Na2SO+ H2O
3. Na2Cr2O+ KCl→ K2Cr2O7 + NaCl 
4. All of the above.
Subtopic:  Chemistry of Mn and Cr Compounds |
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The fusion of chromite ore (FeCr2O4) with Na2CO3 in air gives a yellow solution upon the addition of water. Subsequent treatment with H2SO4 produces an orange solution.

The yellow and orange colours, respectively, are due to the formation of:

1. Na2CrO4 and Na2Cr2O7

2. Cr(OH)3 and Na2Cr2O7

3. Cr2(CO3)3 and Fe2(SO4)3

4. Cr(OH)3 and Na2CrO4

Subtopic:  Chemistry of Mn and Cr Compounds |
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When neutral or faintly alkaline KMnO4 is treated with potassium iodide, the iodide ion is converted into 'X'. The formula of 'X' is:

1. I2

2. IO4-

3. IO3-

4. IO-

Subtopic:  Chemistry of Mn and Cr Compounds |
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HCl is not used to make the medium acidic in oxidation reaction of KMnO4 , because

1. Both HCl and  KMnO4 act as oxidising agents.
2. KMnO4 oxidises HCl into Cl2, which is also an oxidising agent.
3. KMnO4  is a weaker oxidising agent than HCl.
4. KMnO 4 acts as a reducing agent in the presence of HCl.

Subtopic:  Chemistry of Mn and Cr Compounds |
 81%
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A gas that can readily decolorize an acidified KMnO4 solution is:

1. SO2

2. NO2

3. P2O5

4. CO2

Subtopic:  d-Block Elements- Properties & Uses | Chemistry of Mn and Cr Compounds |
 73%
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NEET - 2017
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CrO42- (yellow) changes to Cr2O72- (orange) in pH = x and vice versa in pH = y.

The value of x and y will be:

1. 6, and 8

2. 6, and 5

3. 8, and 6

4. 7, and 7

Subtopic:  Chemistry of Mn and Cr Compounds |
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Which of the following pairs of substances on reaction will not evolve gas?

1. Iron, and H2SO4 (aq)

2. Iron, and steam

3. Copper, and HCl(g)

4. Sodium, and ethyl alcohol

Subtopic:  d-Block Elements- Properties & Uses | Chemistry of Mn and Cr Compounds |
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The oxidation state of chromium in the final product formed by the reaction between KI and acidified potassium dichromate solution will be:

1. +2

2. +3

3. +4

4. +6

Subtopic:  Chemistry of Mn and Cr Compounds |
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Highest oxidation state of manganese in fluoride is +4 (MnF4) but the highest oxidation state in oxides is +7 (Mn2O7). The reason is :

1. Fluorine is more electronegative than oxygen.
2. Fluorine does not possess d orbitals.
3. Fluorine stabilizes lower oxidation state of Mn.
4. In covalent compounds, fluorine can only form a single bond while oxygen forms a double bond.

Subtopic:  Chemistry of Mn and Cr Compounds |
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When KMnO4 solution is added to hot oxalic acid solution, the decolorization is slow in the beginning but becomes instantaneous after some time. This is because : 

1. Mn2+ acts as auto catalyst.

2. CO2 is formed.

3. Reaction is exothermic.

4. MnO4- catalyses the reaction.

Subtopic:  d-Block Elements- Properties & Uses | Chemistry of Mn and Cr Compounds |
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