Select the correct option based on statements below:
Assertion (A): Order and molecularity are the same.
Reason (R): Order is determined experimentally, and molecularity is the sum of the stoichiometric coefficient of the rate-determining the elementary step.
 
1. Both (A) and (R) are true and (R) is the correct explanation of (A).
2. Both (A) and (R) are true but (R) is not the correct explanation of (A).
3. (A) is true but (R) is false.
4. (A) is false but (R) is true.

Subtopic:  Order, Molecularity and Mechanism |
 76%
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Select the correct option based on statements below:

Assertion (A): The order of the reaction can be zero or fractional.
Reason (R): We cannot determine order from the balanced chemical equation.
 
1. Both (A) and (R) are true and (R) is the correct explanation of (A).
2. Both (A) and (R) are true but (R) is not the correct explanation of (A).
3. (A) is true but (R) is false.
4. Both (A) and (R) are false.

Subtopic:  Order, Molecularity and Mechanism |
 58%
From NCERT
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Select the correct option based on statements below:

Assertion (A): The overall order of reaction is the sum of the power of all the reactants in the rate expression.
Reason (R): There are many higher-order reactions.
 
1. Both (A) and (R) are true and (R) is the correct explanation of (A).
2. Both (A) and (R) are true but (R) is not the correct explanation of (A).
3. (A) is true but (R) is false.
4. Both (A) and (R) are false.
Subtopic:  Order, Molecularity and Mechanism |
From NCERT
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Select the correct option based on statements below:

Assertion (A): Base catalyzed hydrolysis of ethyl acetate is a first-order reversible reaction.
Reason (R): The order of reaction always depends on the stoichiometry of the reaction.
 
1. Both (A) and (R) are true and (R) is the correct explanation of (A).
2. Both (A) and (R) are true but (R) is not the correct explanation of (A).
3. (A) is true but (R) is false.
4. Both (A) and (R) are false.
Subtopic:  Order, Molecularity and Mechanism |
 52%
From NCERT
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Select the correct option based on statements below:

Assertion (A): For elementary reactions, the law of mass action and the rate of law expression are generally the same.
Reason (R): The molecularity of an elementary reaction is always one.
 
1. Both (A) and (R) are true and (R) is the correct explanation of (A).
2. Both (A) and (R) are true but (R) is not the correct explanation of (A).
3. (A) is true but (R) is false.
4. Both (A) and (R) are false.
Subtopic:  Order, Molecularity and Mechanism |
 64%
From NCERT
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The correct statements among the following regarding a complex reaction are-

a. Order of the overall reaction is the same as the molecularity of the slowest step.
b. Order of the overall reaction is less than the molecularity of the slowest step.
c. Order of the overall reaction is greater than the molecularity of the slowest step.
d. The molecularity of the slowest step is never zero or non-integer.
 

1. (a, b)
2. (b, c)
3. (c, d)
4. (a, d)

Subtopic:  Order, Molecularity and Mechanism |
 74%
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The correct statements among the following regarding any unimolecular reaction are-

a. Only one reacting species is involved in the rate-determining step
b. The order and the molecularity of the slowest step are equal to one
c. The molecularity of the reaction is one and the order is zero
d. Both molecularity and order of the reaction are one


1. (a, b)
2. (b, c)
3. (c, d)
4. (a, d)

Subtopic:  Order, Molecularity and Mechanism |
 55%
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The graphs that represent a zero-order reaction are:

1. 2.
3. 4.

1. (a, b)
2. (b, c)
3. (c, d)
4. (a, d)

Subtopic:  Order, Molecularity and Mechanism |
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For a general reaction A → B, the plot of concentration of A vs time is given below:

The order of the reaction would be- 

1. Zero 

2. First

3. Half

4. Second

 

 

 

Subtopic:  Order, Molecularity and Mechanism |
 71%
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Match the items in Column I and Column II:

Column I Column II
A. Mathematical expression for the rate of reaction 1. Rate constant
B. Rate of reaction for zero-order reaction is equal to 2. Rate law
C. Units of rate constant for zero-order reaction is same as that of 3. Order of slowest step
D. Order of a complex reaction is determined by 4. Rate of reaction

Codes

A B C D
1. 3 4 1 2
2. 1 2 3 4
3. 2 1 4 3
4. 4 1 3 2
Subtopic:  Order, Molecularity and Mechanism |
 84%
From NCERT
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