Which of the following statements is not correct about the order of a reaction?

1. The order of a reaction can be a fractional number
2. Order of a reaction is experimentally determined quantity
3. The order of a reaction is always equal to the sum of the stoichiometric coefficients of reactants in the balanced chemical equation for a reaction
4. The order of a reaction is the sum of the powers of the molar concentration of the reactants in the rate law expression

Subtopic:  Order, Molecularity and Mechanism |
 83%
From NCERT
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The correct statements among the following regarding any unimolecular reaction are-

a. Only one reacting species is involved in the rate-determining step
b. The order and the molecularity of the slowest step are equal to one
c. The molecularity of the reaction is one and the order is zero
d. Both molecularity and order of the reaction are one


1. (a, b)
2. (b, c)
3. (c, d)
4. (a, d)

Subtopic:  Order, Molecularity and Mechanism |
 55%
From NCERT
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The correct statements among the following regarding a complex reaction are-

a. Order of the overall reaction is the same as the molecularity of the slowest step.
b. Order of the overall reaction is less than the molecularity of the slowest step.
c. Order of the overall reaction is greater than the molecularity of the slowest step.
d. The molecularity of the slowest step is never zero or non-integer.
 

1. (a, b)
2. (b, c)
3. (c, d)
4. (a, d)

Subtopic:  Order, Molecularity and Mechanism |
 74%
From NCERT
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The graphs that represent a zero-order reaction are:

1. 2.
3. 4.

1. (a, b)
2. (b, c)
3. (c, d)
4. (a, d)

Subtopic:  Order, Molecularity and Mechanism |
From NCERT
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Match the graph given in Column I with the order of reaction given in Column II.
More than one item in Column I may be linked to the same item in Column II:

Column I Column II
(a) (a) 1st order
(b) (b) Zero order
(c)
(d)
 
 
(i) (ii) (iii) (iv)
1. (a) (b) (a) (b)
2. (a) (b) (b) (a)
3. (a) (a) (b) (b)
4. (b) (b) (a) (a)
Subtopic:  Order, Molecularity and Mechanism |
 72%
From NCERT
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Match the items in Column I and Column II:

Column I Column II
A. Mathematical expression for the rate of reaction 1. Rate constant
B. Rate of reaction for zero-order reaction is equal to 2. Rate law
C. Units of rate constant for zero-order reaction is same as that of 3. Order of slowest step
D. Order of a complex reaction is determined by 4. Rate of reaction

Codes

A B C D
1. 3 4 1 2
2. 1 2 3 4
3. 2 1 4 3
4. 4 1 3 2
Subtopic:  Order, Molecularity and Mechanism |
 84%
From NCERT
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Select the correct option based on statements below:

Assertion (A): The order of the reaction can be zero or fractional.
Reason (R): We cannot determine order from the balanced chemical equation.
 
1. Both (A) and (R) are true and (R) is the correct explanation of (A).
2. Both (A) and (R) are true but (R) is not the correct explanation of (A).
3. (A) is true but (R) is false.
4. Both (A) and (R) are false.

Subtopic:  Order, Molecularity and Mechanism |
 58%
From NCERT
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Select the correct option based on statements below:
Assertion (A): Order and molecularity are the same.
Reason (R): Order is determined experimentally, and molecularity is the sum of the stoichiometric coefficient of the rate-determining the elementary step.
 
1. Both (A) and (R) are true and (R) is the correct explanation of (A).
2. Both (A) and (R) are true but (R) is not the correct explanation of (A).
3. (A) is true but (R) is false.
4. (A) is false but (R) is true.

Subtopic:  Order, Molecularity and Mechanism |
 76%
From NCERT
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