The molar conductivity of a 0.5 mol/dm3 solution of AgNO3 with electrolytic conductivity of 5.76 × 10–3 S cm–1 at 298 K is:
1. 11.5 S cm2/mol
2. 21.5 S cm2/mol
3. 31.5 S cm2/mol
4. 41.5 S cm2/mol
During the electrolysis of molten sodium chloride, the time required to produce 0.10 mol of chlorine gas using a current of 3 amperes is:
1. 55 minutes
2. 110 minutes
3. 220 minutes
4. 330 minutes
In the electrochemical cell:
\(\mathrm{Z n \left|\right. Z n S O_{4} \left(\right. 0 . 01 M \left.\right) \left|\right. \left|\right. C u S O_{4} \left(\right. 1 . 0 M \left.\right) \left|\right. C u}, \)
the emf of this Daniel cell is E1. When the concentration of ZnSO4 is changed to 1.0 M and that of CuSO4 is changed to 0.01 M, the emf changes to E2. From the following, which one is the relationship between E1 and E2 ?
(Given, \(\frac{RT}{F}\) = 0.059)
1. \(\mathrm{E_{1} < E_{2}}\)
2. \(\mathrm{E_{1} > E_{2}}\)
3. \(\mathrm{E_{2} = 0 \neq E_{1}}\)
4. \(\mathrm{E_{1} = E_{2}}\)
If the Eocell for a given reaction has a negative value, which of the following gives correct relationships for the values of ∆Go and Keq?
1.
2.
3.
4.
The number of electrons delivered at the cathode during electrolysis by a current of 1 ampere in 60 seconds is:
(Charge on electron = 1.60 × 10–19 C)
1.
2.
3.
4.
Consider the change in oxidation state of Bromine corresponding to different emf values as shown in the diagram below:
Then the species undergoing disproportionation is:-
1. | \(\text{BrO}^-_3\) | 2. | \(\text{BrO}^-_4\) |
3. | \(\text{Br}_2\) | 4. | \(\text{HBrO}\) |
The pressure of H2 required to make the potential of H2 - electrode zero in pure water at 298 K is:
1. | 10–12 atm | 2. | 10–10 atm |
3. | 10–4 atm | 4. | 10–14 atm |
A device that converts the energy of combustion of fuels, like hydrogen and methane, directly into electrical energy is known as:
1. | Fuel cell. | 2. | Electrolytic cell. |
3. | Dynamo. | 4. | Ni-Cd cell. |
When 0.1 mol MnO42– is oxidized, the quantity of electricity required to completely oxidise MnO42– to MnO4– is:
1. 96500 C
2. 2 × 96500 C
3. 9650 C
4. 96.50 C
The weight of silver (at.wt. = 108) displaced by a quantity of electricity which displaces 5600 mL of O2 at STP will be:
1. 5.4 g
2. 10.8 g
3. 54.0 g
4. 108.0 g