A solution that has the highest boiling point among the following is:
1. 1.0 M NaOH
2. 1.0 M Na2SO4
3. 1.0 M NH4NO3
4. 1.0 M KNO3
The unit of Ebullioscopic constant is:
1. K kg mol–1 or K (molality)–1
2. mol kg K–1 or K–1 (molality)
3. kg mol–1 K–1 or K–1 (molality)–1
4. K mol kg–1 or K (molality)
The incorrect statement among the following is:
| 1. | Units of atmospheric pressure and osmotic pressure are the same. |
| 2. | In reverse osmosis, solvent molecules move through a semipermeable membrane from a region of lower concentration of solute to a region of higher concentration. |
| 3. | The value of molal depression constant depends on nature of solvent. |
| 4. | Relative lowering of vapour pressure, is a dimensionless quantity. |
Match the laws/colligative properties given in Column-I with expressions given in Column-II.
| Column-I | Column-II | ||
| A. | Raoult’s law | I. | \(\mathrm{\pi=C R T}\) |
| B. | Osmotic pressure | II. | \(\Delta \mathrm{T}_{\mathrm{f}}=\mathrm{K}_{\mathrm{f}} \mathrm{~m}\) |
| C. | Elevation of boiling point | III. | \(\mathrm{p=x_1 p_1^0+x_2 p_2^0}\) |
| D. | Depression in freezing point | IV. | \(\Delta \mathrm{T}_{\mathrm{b}}=\mathrm{K}_{\mathrm{b}} \mathrm{~m}\) |
Codes:
| A | B | C | D | |
| 1. | I | III | IV | I |
| 2. | I | II | III | IV |
| 3. | I | IV | III | II |
| 4. | III | I | IV | II |
Select the correct option based on statements below:
| Assertion (A): | When methyl alcohol is added to water, boiling point of water increases. |
| Reason (R): | When a volatile solute is added to a volatile solvent, elevation in boiling point is observed. |
| 1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
| 2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
| 3. | (A) is True but (R) is False. |
| 4. | Both (A) and (R) are False. |