Match the laws given in Column I with expressions given in Column II.

Column I Column II
A. Raoult’s law 1. π = CRT
B. Osmotic pressure  2. ΔTf=Kfm
C. Elevation of boiling point 3. p=x1p10 +x2p20
D. Depression in freezing point 4. ΔTb=Kbm

Codes

A B C D
1. 2 3 4 1
2. 1 2 3 4
3. 1 4 3 2
4. 3 1 4 2
Subtopic:  Elevation of Boiling Point | Depression of Freezing Point |
 93%
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The molality of a solution containing a certain solute, if there is a freezing point depression of 0.184 °C, is-

(Kf = 18.4)

1. 0.01 m

2. 10 m

3. 0.05 m

4. 100 m

Subtopic:  Depression of Freezing Point |
 89%
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The freezing point of depression constant (Kf ) of benzene is 5.12 K kg mol-1. The freezing point depression for the solution of molality 0.078 m containing a non-electrolyte solute in benzene is-
(rounded off upto two decimal places):
1. 0.80 K
2. 0.40 K
3. 0.60 K
4. 0.20 K

Subtopic:  Depression of Freezing Point |
 87%
From NCERT
NEET - 2020
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When 20 g of naphthoic acid (C11H8O2) is dissolved in 50 g of benzene (Kf = 1.72 K kg mol–1),
a freezing point depression of 2 K is observed. The van’t Hoff factor (i) is –

1. 0.5  2. 1
3. 4. 3
Subtopic:  Depression of Freezing Point |
 82%
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Freezing point of an aqueous solution is -0.166°C. Elevation of boiling point of same solution would be-

(Kb = 0.512 K m-1 and Kf = 1.66 K m-1)

1. 0.18°C 2. 0.05°C
3. 0.09°C 4. 0.23°C
Subtopic:  Depression of Freezing Point |
 85%
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In comparison to a 0.01 M solution of glucose, the depression in the freezing point of a 0.01 M MgCl2 solution will be  -

1. Same 2. About twice
3. About three times 4. About six times
Subtopic:  Depression of Freezing Point |
 81%
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A solution containing 6.8 g of a non-ionic solute in 100 g of water was found to freeze at −0.93 oC. The freezing point depression constant of water is 1.86. The molecular weight of the solute is-

1. 13.6 m 2. 34 m
3. 68 m 4. 136 m
Subtopic:  Depression of Freezing Point |
 77%
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The freezing point depression constant for water is 1.86 oC m-1. If 5.00 g Na2SOis dissolved in 45.0 g H2O, the freezing point is changed by -3.82 oC. The van’t Hoff factor for Na2SO4 is:

1. 2.63 2. 3.11
3. 0.381 4. 2.05
Subtopic:  Depression of Freezing Point |
 69%
From NCERT
AIPMT - 2011
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The graph, amongst the following, that represents depression in the freezing point is:

1.
2.
3.
4. None of the above
Subtopic:  Depression of Freezing Point |
 72%
From NCERT
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A solution of sucrose (molar mass = 342 g mol-1) has been prepared by dissolving 68.5 g of sucrose in 1000 g of water.

The freezing point of the solution obtained will be:

 (Kf for water = 1.86 K kg mol-1)

1. -0.372 °C

2. 0.372 °C

3. 0.572 °C

4. -0.572 °C

Subtopic:  Depression of Freezing Point |
 71%
From NCERT
NEET - 2010
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