The van't Hoff factor of a 0.005 M aqueous solution of KCl is 1.95. The degree of ionisation of KCl is-

1. 0.95

2. 0.97

3. 0.94

4. 0.96

Compound PdCl₄.6H₂O is a hydrated complex, 1 molal aqueous solution of it has freezing point 269.28 K. Assuming 100 % ionization of complex, the molecular formula of the complex is-

(K_f for water = 1.86 K kg mole^-1)

1. [Pd(H₂O)₆]Cl₄

2. [Pd(H₂O)₄Cl₂]Cl₂.2H₂O

3. [Pd(H₂O)₃Cl₃]Cl.3H₂O

4. [Pd(H₂O)Cl₄]4H₂O

The temperature dependent term among the following is -

A solution of sucrose (molar mass = 342 g mol^-1) has been prepared by dissolving 68.5 g of sucrose in 1000 g of water.

The freezing point of the solution obtained will be:

 (K_f for water = 1.86 K kg mol^-1)

1. -0.372 $°$C

2. 0.372 $°$C

3. 0.572 $°$C

4. -0.572 $°$C

If partial pressure of oxygen is 0.5 atm and K_H = 1.4 × 10^-3 M/atm, then the amount of oxygen dissolved in 100 ml water at 298K is-

Total vapour pressure of a mixture of 1 mol A (p_A°  = 150 torr) and 2 mol B (${\mathrm{p}}_{\mathrm{B}}^{°}$ = 240 torr) is 200 torr. In this case:-

1. There is a positive deviation from Raoult's law
2. There is a negative deviation from Raoult's law
3. There is no deviation from Raoult's law
4. None of these 

The relative lowering of vapour caused by dissolving 71.3 g of a substance in 1000 g of water is 7.13 x 10^-3. The molecular mass of the substance is-

1. 180 g mol^-1

2. 18 g mol^-1

3. 1.8 g mol^-1

4. 360 g mol^-1

A solution of acetone in ethanol:

1. Shows a negative deviation from Raoult's law.

2. Shows a positive deviation from Raoult's law.

3. Behaves like a near ideal solution.

4. Obeys Raoult's law.

The density of H₂SO₄ solution is 1.84 g ml^–1. In a 1 litre solution if H₂SO₄ is 93 % by (w/v) then the molality of the solution is -

Lowering in vapour pressure is the highest for:

1. 0.2 m urea

2. 0.1 m glucose

3. 0.1 m MgSO₄

4. 0.1 m BaCl₂