Henry’s law constant for the solution of methane in benzene at 298 K is 4.27 × 105 mm Hg. The mole fraction of methane in benzene at 298 K under 760 mm Hg will be:

1. 1.85 × 105

2. 192 × 104

3. 178 × 105

4. 18.7 × 10–5

Subtopic:  Concentration Terms & Henry's Law |
 73%
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100 g of liquid A (molar mass 140 g mol–1) was dissolved in 1000 g of liquid B (molar mass 180 g mol–1). The vapour pressure of pure liquid B was found to be 500 torrIf the total vapour pressure of the solution is 475 torr, the vapour pressure of pure liquid A will be -

1. 326 torr

2. 226 torr 

3. 360.7 torr

4. 280.7 torr

Subtopic:  Raoult's Law |
 51%
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The amount of CaCl2 (i = 2.47) dissolved in 2.5 litre of water such that its osmotic pressure is 0.75 atm at 27 °C is-

1. 1.02 g

2. 4.35 g

3. 2.87 g

4. 3.42 g

Subtopic:  Osmosis & Osmotic Pressure |
 60%
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If 22 g of benzene is dissolved in 122 g of CCl4, the mass percentage of CCl4 and benzene respectively are-

1. 15.28 %, 84.72 % 

2. 84.72 %, 15.28 %

3. 8.72 %, 91.28 %

4. 91.28 %, 8.72 %

Subtopic:  Concentration Terms & Henry's Law |
 65%
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The type of inter molecular interactions present in

(a) Methanol and Acetone (i) Van der Waal’s forces of attraction
(b) Acetonitrile and Acetone (ii) ion-dipole interaction
(iii) dipole-dipole interaction
 
(a) (b)
1. (iii) (ii)
2. (ii) (ii)
3. (iii) (iii)
4. (iii) (i)
Subtopic:  Azeotrope |
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To make 2.5 kg of 0.25 m aqueous solution, the mass of urea required is-

1. 73 g 2. 37 g
3. 48 g 4. 24 g
Subtopic:  Concentration Terms & Henry's Law |
 78%
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The solubility of H2S in water at STP is 0.195 m. The value of Henry's constant is-

1. 274 atm 2. 285 atm
3. 295 atm 4. 278 atm
Subtopic:  Concentration Terms & Henry's Law |
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The vapour pressure of water in the solution having 50 g of urea dissolved in 850 g of water is-

(Vapor pressure of pure water at 298 K is 23.8 mm Hg) 

1. 23.40 mm of Hg

2. 33.46 mm of Hg

3. 12.76 mm of Hg

4. 87.12 mm of Hg

Subtopic:  Relative Lowering of Vapour Pressure |
 72%
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The solubility of a gas in a liquid decreases with an increase in temperature because:

1. Dissolution of a gas in a liquid is an endothermic process. 
2. Dissolution of a gas in a liquid is an exothermic process. 
3. Gases are highly compressible.
4. All of the above.
Subtopic:  Introduction & Colligative properties |
 69%
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To minimise the painful effects accompanying deep sea diving, oxygen diluted with less soluble helium gas is used as breathing gas by the divers. This is an example of the application of - 

1. Raoult's law 2. Henry's law
3. Ideal gas Equation 4. All of the above
Subtopic:  Concentration Terms & Henry's Law |
 82%
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