Match column I with Column-II.
 
Column I
(Molecules)
COLUMN II
(Nature of molecule) 
a. (CH3)3N: i. Electrophile
b. \(H_3C-\overset{+}{C}=O\) ii. Nucleophile
c. \(\overset{+}{N}O_2\)
d. H2N:-
 
a b c d
1. ii ii ii i
2. ii ii ii ii
3. ii i i ii
4. ii i ii ii

Subtopic:  Nucleophile & Electrophile |
 84%
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Consider the following molecule.

(a) H3C-H, H3C-Br

(b) H3C-NH2, H3C-OH

(c) H3C-OH, H3C-SH

The bond which is more polar in the given pairs of molecules is-

1. C-H bond is more polar than C-Br bond; C-O is more polar than C-N and C-S bond
2. C-Br bond is more polar than C-H bond; C-O is more polar than C-N and C-S bond
3. C-Br bond is more polar than C-H bond; C-N is more polar than C-O and C-O bond is more polar than C-S
4. None of the above


 

Subtopic:  Aromaticity & Polarity |
 73%
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Consider the following compound:
 
Carbon with minimum impact of negative inductive effect of Br is -

1. C1
2. C2
3. C3
4. All have same inductive effect


 

Subtopic:  Electron Displacement Effects |
 89%
From NCERT
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The correct resonance structures of CH3COO- among the following are-
 

1.
2.
3.
4.





 

Subtopic:  Electron Displacement Effects |
 83%
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Consider the possible resonating structures of CH2=CH–CHO is as follows:


The correct sequence of stability is-

1. II > I > III
2. III > I > II
3. I > III > II
4. I > II > III

Subtopic:  Electron Displacement Effects |
 78%
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Consider the resonance structure of CH3COOCHas follows:



The correct statement among the following is-

1. I and II cannot be the major contributors to the real structure of CH3COOCH3
2. I and II can be the major contributors to the real structure of CH3COOCH3
3. I is more stable than II.
4. None of the above





 

Subtopic:  Electron Displacement Effects |
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The correct order of stability of following carbocation is-

1. b > a > c
2. a > c > b
3. a > b > c
4. c > b > a

Subtopic:  Electron Displacement Effects | Reaction Intermediates ; Preparation & Properties |
 93%
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On complete combustion, 0.246 g of an organic compound gave 0.198g of carbon dioxide and 0.1014g of water.
The percentage composition of carbon and hydrogen in the compound  are respectively-

1. 21.95 %; 4.58 %
2. 33.46 %; 3.14 %
3. 42.15 %; 2.61 %
4. 25.24 %; 3.98 %

Subtopic:  Quantitative Analysis of Organic Compounds |
 70%
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In Dumas’ method for estimation of nitrogen, 0.3g of an organic compound gave 50mL of nitrogen collected at 300K temperature and 715mm pressure. The percentage composition of nitrogen in the compound is-

(Aqueous tension at 300K=15 mm)

1. 21.43%

2. 25.13%

3. 19.46%

4. 17.46%

Subtopic:  Quantitative Analysis of Organic Compounds |
 62%
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During estimation of nitrogen present in an organic compound, the ammonia evolved from 0.5 g of the compound in Kjeldahl’s estimation of nitrogen, neutralized 10 mL of 1 M H2SO4. The percentage of nitrogen in the compound is-

1. 46.0 %

2. 51.0%

3. 56.0%

4. 49.0%

Subtopic:  Quantitative Analysis of Organic Compounds |
 73%
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