The decreasing order of nucleophilicity among the given nucleophiles is:
(A) | (B) | ||
(C) | (D) |
1. (C), (B), (A), (D)
2. (B), (C), (A), (D)
3. (D), (C), (B), (A)
4. (A), (B), (C), (D)
The increasing order of stability of the following free radicals is:
1. | \(\small{({CH}_3})_2 \dot{{C}}H<{({CH}_3})_3 \dot{{C}}<{({C}_6 {H}_5})_2 \dot{{C}}H <{({C}_6 {H}_5})_3 \dot{{C}}\) |
2. | \(\small({{C}_{6} {H}_{5})}_{3} \dot{{C}}<({{C}_{6} {H}_{5})}_{2} \dot{{C}} {H}<({{CH}_{3})}_{3} \dot{{C}}<({{CH}_{3})}_{2} \dot{{C}}H\) |
3. | \(\small({{C}_{6} {H}_{5})}_{2} \dot{{C}} {H}<({{C}_{6} {H}_{5})}_{3} \dot{{C}}<({{CH}_{3})}_{3} \dot{{C}} <({{CH}_{3})}_{2} \dot{{C}}H \) |
4. | \(\small({{CH}_{3})}_{2} \dot{{C}} {H}<({{CH}_{3})}_{3} \dot{{C}}<({{C}_{6} {H}_{5})}_{3} \dot{{C}} <({{C}_{6} {H}_{5})}_{2} \dot{{CH}}\) |
The ammonia evolved from the treatment of 0.30 g of an organic compound for the estimation of nitrogen was passed in 100 mL of 0.1 M sulphuric acid. The excess acid required 20 mL of 0.5 M sodium hydroxide solution for complete neutralization. The percentage of nitrogen in the organic compound is:
1. 46.6 %
2. 50.4 %
3. 42.8 %
4. 40.5 %
The IUPAC name of the following compound is:
1. 3, 3-Dimethyl-1-hydroxycyclohexane
2. 1,1-Dimethyl-3-hydroxycyclohexane
3. 3,3-Dimethyl-1-cyclohexanol
4. 1,1-Dimethyl-3-cyclohexanol
The compound that does not have sp2 hybridized carbon among the following is:
1. Acetone
2. Acetic acid
3. Acetonitrile
4. Acetamide
In a given organic compound of molar mass
108 g mol-1 , C, H, and N atoms are present in a 9: 1: 3.5 by weight ratio.
The molecular formula of the organic compound is:
1. C6H8N2
2. C7H10N
3. C5H6N3
4. C4H18N3
Choose the compound with incorrect IUPAC nomenclature among the following.
1. | Ethylbutanoate | |
2. | 3-Methylbutanal | |
3. | 2-Methyl-3-pentanone | |
4. | 2-Methyl-3-butanol |
Given the following benzyl/allyl system:
1. (CH3)3C- > (CH3)2CH- > CH3CH2-
2. CH3CH2- >(CH3)2CH- > (CH3)3C-
3. (CH3)2CH- > CH3CH2- > (CH3)3C-
4. (CH3)3C- > CH3CH2- > (CH3)2CH-
What properties do free radicals exhibit due to their unpaired electron?
1. Cations
2. Anions
3. Chemically non-reactive
4. Chemically reactive
Following types of compounds (as I, II) are studied in terms of isomerism in:
(I) | CH3CH=CHCH3 |
(II) |
1. Chain isomerism
2. Position isomerism
3. Conformers
4. Stereisomerism