Given below are two statements :
Statement I: Ferromagnetism is considered as an extreme form of paramagnetism.
Statement II: The number of unpaired electrons in a \(Cr^{2+}\)ion (Z=24) is the same as that of a \(Nd^{3+}\) ion (Z=60)

In the light of the above statements, choose the correct answer from the options given below :
1. Statement I is True but Statement II is False.
2. Statement I is False but Statement II is True.
3. Both Statement I and Statement II are True.
4. Both Statement I and Statement II are False.
Subtopic:  d-Block Elements- Properties & Uses | f-Block Elements- Properties & Uses |
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The E° value for the Mn3+/Mn2+ couple is more positive than that of Cr3+/Cr2+ or Fe3+/Fe2+ due to change of:
1. d5 to d2 configuration 2. d4 to d5 configuration
3. d3 to d5 configuration 4. d5 to d4 configuration
Subtopic:  d-Block Elements- Properties & Uses |
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Which of the following ions have the same 'spin-only' magnetic moment?

A. Ti+3 B. Cr2+
C. Mn2+ D. Fe2+
E. Sc3+

Choose the most appropriate answer from the options given below:

1. A and E only 2. B and C only
3. A and D only 4. B and D only
Subtopic:  d-Block Elements- Properties & Uses |
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The pair of lanthanoid ions, consisting of elements which are diamagnetic, is:
1. Ce3+ and Eu2+
2. Gd3+ and Eu3+
3. Pm3+ and Sm3+
4. Ce4+ and Yb2+
Subtopic:  f-Block Elements- Properties & Uses |
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The behaviour of samarium (Z=62) is very much like europium (Z=63), since both elements:
1. exhibit +2 and +3 oxidation states.
2. have \(4 f^5 6 s^2 \) and \(4 f^6 6 s^2\) electronic configurations, respectively.
3. have \(4 f^7 6 s^2\) and \(4 f^8 6 s^2\) electronic configurations, respectively.
4. have the same atomic radii.
Subtopic:  f-Block Elements- Properties & Uses |
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Match List-I with List-II 
List-I
(Element)
List-II
(Most Common oxidation state/s)
A.  \(\mathrm{Fe}\) I.  +2, +7 
B.  V II. +3, +2 
C.  \(\mathrm{Mn}\) III. +4
D.  \(\mathrm{Ti}\) IV.  +5
Choose the correct answer from the options given below:
 
1. A-II, B-IV, C-I, D-III 2. A-IV, B-II, C-I, D-III
3. A-II, B-I, C-IV, D-III 4. A-I, B-IV, C-II, D-III
Subtopic:  d-Block Elements- Properties & Uses |
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The number of moles of \(\mathrm{MnO}_4^{-}\) being reduced to \(\mathrm{Mn}^{2+}\) under acidic conditions by \(4.517 \times 10^{24}\) electrons are:
1. 1.5 moles 2. 7.5 moles
3. 2.5 moles 4. 5.0 moles
Subtopic:  Chemistry of Mn and Cr Compounds |
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Which of the following pairs of ions will have the same spin only magnetic moment values within the pair?
A. \(\mathrm{Zn ^{2+}, Ti ^{2+}}\)
B. \(\mathrm{Cr ^{2+}, Fe ^{2+}}\)
C. \(\mathrm{Ti ^{3+}, Cu ^{2+}}\)
D. \(\mathrm{V ^{2+}, Cu ^{+}}\)
Choose the correct answer from the options given below:
1. C and D only  2. A and D only 
3. A and B only  4. B and C only 
Subtopic:  d-Block Elements- Properties & Uses |
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Which of the following set of ions act as oxidizing agents?

1. \(\mathrm{Ce}^{4+} \) and \(\mathrm{Tb}^{4+}\)
2. \(\mathrm{La}^{3+} \) and \(\mathrm{Lu}^{3+}\)
3. \(\mathrm{Eu}^{2+} \) and \(\mathrm{Yb}^{2+}\)
4. \(\mathrm{Eu}^{2+} \) and \(\mathrm{Tb}^{4+}\)
Subtopic:  d-Block Elements- Properties & Uses |
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The UV-visible absorption bands in the spectra of lanthanoid ions are 'X', probably because of the excitation of electrons involving 'Y'. The 'X' and 'Y', respectively, are:

1. Broad and f orbitals
2. Narrow and f orbitals
3. Broad and d and f orbitals
4. Narrow and d and f orbitals
Subtopic:  f-Block Elements- Properties & Uses |

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