The reaction below is an example of:

CH3COOC2H5   +   H2O   \(\xrightarrow[]{H^{+}}\) CH3COOH  +   C2H2OH
Ethyl acetate                           Acetic acid     Ethyl alcohol



1. Pseudo-first-order reaction

2. First-order reaction

3. Second order reaction

4. Third-order reaction

Subtopic:  Order, Molecularity and Mechanism |
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Match the items of Column I with items of Column II

Column I
(Concepts Related to Chemical Kinetics
)
Column II
(Related Terms)
A. Mathematical expression for the rate of reaction 1. Rate constant
B. Rate of reaction for zero-order reaction is equal to 2. Rate law
C. Units of rate constant for zero-order reaction is same as that of 3. Order of slowest step
D. Order of a complex reaction is determined by 4. Rate of reaction


Codes:

A B C D
1. 3 4 1 2
2. 1 2 3 4
3. 2 1 4 3
4. 4 1 3 2
Subtopic:  Order, Molecularity and Mechanism |
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When the initial concentration of a reactant is doubled in a reaction, its half-life period is not affected. The order of the reaction will be:
1. 0
2. 1
3. 1.5
4. 2 

Subtopic:  Order, Molecularity and Mechanism |
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The kinetic data for the reaction: 2A + B2 → 2AB are as given below

[A]/mol L-1 [B2]/mol L-1 Rate/mol L-1s-1
0.5 1.0 2.5 × 10-3
1.0 1.0 5.0 × 10-3
0.5 2.0 1 × 10-2

The order of reaction with respect to A and B2 is, respectively:

1. 1 and 2 2. 2 and 1
3. 1 and 1 4. 2 and 2
Subtopic:  Order, Molecularity and Mechanism |
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Select the correct option based on statements below:
Assertion (A): Order and molecularity are the same.
Reason (R): Order is determined experimentally, and molecularity is the sum of the stoichiometric coefficient of the rate-determining the elementary step.
   
1. Both (A) and (R) are True and (R) is the correct explanation of (A).
2. Both (A) and (R) are True but (R) is not the correct explanation of (A).
3. (A) is True but (R) is False.
4. (A) is False but (R) is True.
Subtopic:  Order, Molecularity and Mechanism |
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Match the graph given in Column I with the order of reaction given in Column II.
More than one item in Column I may be linked to the same item in Column II:

Column I Column II
(i) (a) 1st order
(ii) (b) Zero order
(iii)
(iv)
 
 
(i) (ii) (iii) (iv)
1. (a) (b) (a) (b)
2. (a) (b) (b) (a)
3. (a) (a) (b) (b)
4. (b) (b) (a) (a)
Subtopic:  Order, Molecularity and Mechanism |
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Select the correct option based on statements below:

Assertion (A): For elementary reactions, the law of mass action and the rate of law expression are generally the same.
Reason (R): The molecularity of an elementary reaction is always one.
 
1. Both (A) and (R) are true and (R) is the correct explanation of (A).
2. Both (A) and (R) are true but (R) is not the correct explanation of (A).
3. (A) is true but (R) is false.
4. Both (A) and (R) are false.
Subtopic:  Order, Molecularity and Mechanism |
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For a given reaction the concentration of the reactant plotted against time gave a straight line with negative slope.

The order of the reaction will be:

1. 3                                                      

2. 2

3. 1                                                      

4. 0

Subtopic:  Order, Molecularity and Mechanism |
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A reaction A2 + B2  2AB occurs by the following mechanism:

A2  A + A               .....(slow)

A + B2  AB + B       .....(fast)

A + B  AB               .....(fast)

Its order would be:

1. 3/2

2. 1

3. 0

4. 2

Subtopic:  Order, Molecularity and Mechanism |
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The mechanism of a hypothetical reaction

X+ Y→ 2XY  is given below: 
(i) X→ X + X (Fast)
(ii) X + Y2  ⇄  XY + Y (slow)
(iii) X + Y → XY (Fast)

The overall order of the reaction will be:

1. 2

2. 0

3. 1.5

4. 1

Subtopic:  Order, Molecularity and Mechanism |
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