The average S–F bond energy in kJ mol–1 of SF6 is:

 [The values of standard enthalpy of formation of
SF6(g), S(g), and F(g) are –1100, 275, and 80 kJmol–1 respectively.]

1. 309 kJ mol–1 2. 313 kJ mol–1
3. 305 kJ mol–1 4. 318 kJ mol–1
Subtopic:  Thermochemistry |
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Lattice energy and enthalpy of the solution of NaCl are 788 kJ mol–1 and 4 kJ mol–1 , respectively. The hydration enthalpy of NaCl is:
1. –780 kJ mol–1
2. –784 kJ mol–1
3. 780 kJ mol–1
4.  784 kJ mol–1

Subtopic:  Thermochemistry |
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The standard enthalpy of formation of NH3 is -46 0. kJ mol−1. If the enthalpy of formation of H2 from its atoms is -436 kJ mol−1 and that of N2 is -712 kJ mol-1, the average bond enthalpy of N − H bond in NH3 is:

1. 1102kJmol1

2. 964kJmol1

3. +352kJmol1

4. +1056kJmol1

Subtopic:  Thermochemistry |
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The enthalpies of combustion of carbon and carbon monoxide are -393.5 and -283 kJ mol-1 respectively. The enthalpy of the formation of carbon monoxide per mole is:

1. 110.5 kJ

2. 676.5 kJ

3. -676.5 kJ

4. -110.5 kJ

Subtopic:  Hess's Law | Thermochemistry |
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If at 298 K the bond energies of C-H, C-C, C = C and H-H bonds are respectively 414, 347, 615, and 435 kJ mol–1, the value of enthalpy change for the reaction at 298 K will be:

\(\mathrm{H}_{2} \mathrm{C}=\mathrm{CH}_{2}(g)+\mathrm{H}_{2}(g) \longrightarrow \mathrm{H}_{3} \mathrm{C}-\mathrm{CH}_{3}(g)\)

1. +250 kJ 

2. –250 kJ 

3. +125 kJ 

4. –125 kJ 

Subtopic:  Thermochemistry |
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An athlete is given 100 g of glucose energy equivalent to 1560 kJ to utilize 50 % of this gained energy in an event. Enthalpy of evaporation of H2O is 44 kJ/mol. In order to avoid storage of energy in the body the mass of water (in g) he would perspire is:
(Round off the nearest Integer)

1. 325 g
2. 319 g
3. 298 g
4. 345 g
Subtopic:  Thermochemistry |
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Calculate the standard enthalpy of formation (\(\Delta_fH^\circ\)) for 2 moles of liquid benzene (\(\mathrm{{C_6H_6}_{(l)}}\)) at 25°C, based on the given thermodynamic data.
Given Data:
\(\Delta _c\mathrm H\mathrm{(C_6H_6}_\mathrm{(l)})~= -3264.6~ \mathrm{~kJ} / \mathrm{mol}\)
\(\Delta _c\mathrm H\mathrm{(C}_\mathrm{(s)})~= -393.5~ \mathrm{~kJ} / \mathrm{mol}\)
\(\Delta _f\mathrm H\mathrm{(H_2O}_\mathrm{(l)})~= -285.83~ \mathrm{~kJ} / \mathrm{mol}\)

1. \(-~92.22 \mathrm{~kJ} / \mathrm{mol}\)
2. \(-46.11 \mathrm{~kJ} / \mathrm{mol}\)
3. \(+~92.22 \mathrm{~kJ} / \mathrm{mol}\)
4. \(+46.11 \mathrm{~kJ} / \mathrm{mol}\)
Subtopic:  Thermochemistry |
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Consider the following reactions:
\(\mathrm{S}_{(\mathrm{~g})}+\frac{3}{2} \mathrm{{O}_2}_{(\mathrm{~g})} \rightarrow \mathrm{{SO}_3}_{(\mathrm{~g})}+2 \mathrm{x} \mathrm{~kcal}\)

\(\mathrm{{SO}_2}_{(\mathrm{~g})}+\frac{1}{2} \mathrm{{O}_2}_{(\mathrm{~g})} \rightarrow \mathrm{{SO}_3}_{(\mathrm{~g})}+\mathrm{y} \mathrm{~kcal}\)
The heat of formation of SO2(g) is given by:
1. \(\dfrac{2 \mathrm{x}}{\mathrm{y}} \mathrm{kcal}\) 2. y - 2x kcal
3. 2x + y kcal 4. x + y kcal
Subtopic:  Thermochemistry |
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