A process among the following shows decrease in entropy is :

1. \(2 \text H \left(g\right)\rightarrow\text H_{2} \left(g\right)\)

2. Evaporation of water

3. Expansion of a gas at a constant temperature

4. Sublimation of solid to gas

Under the isothermal condition, a gas at \(300 \mathrm{~K}\) expands from \(0.1 \mathrm{~L}\) to \(0.25 \mathrm{~L}\) against a constant external pressure of 2 bar. The work done by the gas is:

Assuming each reaction is carried out in an open container,
Reaction that shows ΔH=ΔE is :

1. $H_2\left(g\right)+B{r}_2\left(g\right)\to 2HBr\left(g\right)$

2. $C\left(s\right)+2H_{2}O\left(g\right)\to 2H_2\left(g\right)+C{O}_2\left(g\right)$

3. $PC{l}_5\left(g\right)\to PC{l}_3\left(g\right)+C{l}_2\left(g\right)$

4. $2CO\left(g\right)+O_2\left(g\right)\to 2C{O}_2\left(g\right)$

The bond energy of H—H and Cl-Cl is 430 kJ
mol^-1 and 240 kJ mol^-1 respectively and ΔH_f for HCl is -90 kJ mol^-1. The bond enthalpy of HCl is:

1. 290 $kJ$ $mo{l}^{-1}$

2. 380 $kJ$ $mo{l}^{-1}$

3. 425 $kJ$ $mo{l}^{-1}$

4. 245 $kJ$ $mo{l}^{-1}$

The values of ΔH and ΔS for the given reaction are 170 kJ and 170 JK^-1, respectively.
C_(graphite) + CO₂(g)→2CO(g) 
This reaction will be spontaneous at:

1. 710 K
2. 910 K
3. 1110 K
4. 510 K

Give the following bond energies:
H—H bond energy: 431.37 kJ mol^-1 
C=C bond energy: 606.10 kJ mol^-1 
C—C bond energy: 336.49 kJ mol^-1 
C—H bond energy: 410.50 kJ mol^-1 

Enthalpy for the following reaction will be:

Standard entropies of X₂, Y₂ and XY₃ are 60, 40 and 50JK^-1mol^-1 respectively. For the reaction 
$\frac{1}{2}{\mathrm{X}}_2$ $+$ $\frac{3}{2}{\mathrm{Y}}_2$ $$ $\leftrightharpoons$ ${\mathrm{XY}}_3$ $;$ $∆\mathrm{H}$ $=$ $-30$ $\mathrm{kJ}$ to be at equilibrium, the temperature should be:

1. 750 K

2. 1000 K

3. 1250 K

4. 500 K