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Given the following reaction:
\(4H(g)\)→  \(2 H_{2}\)\((g)\)
The enthalpy change for the reaction is -869.6 kJ. The dissociation energy of the H-H bond is:
1. -869.6 kJ
2. +434.8kJ
3. +217.4kJ
4. -434.8 kJ

Subtopic:  Enthalpy & Internal energy |
 68%
Level 2: 60%+
AIPMT - 2011
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Give the following bond energies:
H—H bond energy: 431.37 kJ mol-1 
C=C bond energy: 606.10 kJ mol-1 
C—C bond energy: 336.49 kJ mol-1 
C—H bond energy: 410.50 kJ mol-1 

Enthalpy for the following reaction will be:

1. 1523.6 kJ mol-1
2. -243.6 kJ mol-1
3. -120.0 kJ mol-1
4. 553.0 kJ mol-1
Subtopic:  Thermochemistry |
 76%
Level 2: 60%+
AIPMT - 2009
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The values of ΔH and ΔS for the given reaction are 170 kJ and 170 JK-1, respectively.
C(graphite) + CO2(g)→2CO(g) 
This reaction will be spontaneous at:

1. 710 K
2. 910 K
3. 1110 K
4. 510 K

Subtopic:  Gibbs Energy Change |
 88%
Level 1: 80%+
AIPMT - 2009
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Which of the following are not state functions? 
(I) q + W 
(II) q 
(III) W 
(IV) H - TS

1. (I) and (IV)
2. (II), (III) and (IV)
3. (I), (II) and (III)
4. (II) and (III)
Subtopic:  Gibbs Energy Change |
 79%
Level 2: 60%+
AIPMT - 2008
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For the gas phase reaction, 
 PCl5(g)PCl3(g)+Cl2(g)
which of the following conditions is correct?

1. ΔH = 0 and ΔS < 0

2. ΔH > 0 and ΔS > 0

3. ΔH < 0 and ΔS < 0

4. ΔH > 0 and ΔS < 0

Subtopic:  Gibbs Energy Change |
 83%
Level 1: 80%+
AIPMT - 2008
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Bond dissociation enthalpy of H2, Cl2, and HCl are 434, 242, and 431 kJ mol1 respectively. Enthalpy of formation of HCl is:

1. 93 kJ mol-1
2. - 245 kJ mol-1
3. -93 kJ mol-1
4. 245 kJ mol-1

Subtopic:  Thermochemistry |
 66%
Level 2: 60%+
AIPMT - 2008
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Consider the following reactions: 

(i) H+(aq) + OH-(aq) → H2O(l)
ΔH = -x1 kJmol-1
(ii) H2(g) + 1/2O2(g) → H2O(l)
ΔH = -x2 kJmol-1
(iii) CO2(g) + H2(g) → CO (g) + H2O(l)
ΔH = -x3 kJmol-1
(iv) C2H2(g) + 5/2O2(g) →  2CO+ H2O(l)
ΔH = -x4 kJmol-1


Enthalpy of formation of H2O(l) is :

1. -x3 kJ mol-1

2. -x4 kJ mol-1

3. -x1 kJ mol-1

4. -x2 kJ mol-1

Subtopic:  Thermochemistry |
 77%
Level 2: 60%+
AIPMT - 2007
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The bond energy of H—H and Cl-Cl is 430 kJ
mol-1 and 240 kJ mol-1 respectively and ΔHf for HCl is -90 kJ mol-1. The bond enthalpy of HCl is:

1. 290 kJ mol-1

2. 380 kJ mol-1

3. 425 kJ mol-1

4. 245 kJ mol-1

Subtopic:  Thermochemistry |
 62%
Level 2: 60%+
AIPMT - 2007
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The enthalpy and entropy change for the reaction: Br2 (l) + Cl2 (g) →2BrCl(g), are 30kJ mol-1 and 105 JK-1 mol-1 respectively. The temperature at which the reaction will be in equilibrium is: 

1. 285.7 K

2. 273 K

3. 450 K

4. 300 K

Subtopic:  Gibbs Energy Change |
 74%
Level 2: 60%+
AIPMT - 2006
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The enthalpy of combustion of H2, cyclohexene (C6H10) and cyclohexane (C6H12) are -241, -3800 and -3920 kJ per mol respectively. Heat of hydrogenation of cyclohexene is:

1. -121 kJ per mol

2. +121 kJ per mol

3. +242 kJ per mol

4. -242 kJ per mol

Subtopic:  Thermochemistry |
 59%
Level 3: 35%-60%
AIPMT - 2006
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