A buffer solution is prepared in which the concentration of NH3 is 0.30 M and the concentration of  NH4+  is 0.20 M. If the equilibrium constant, Kb for NH3 equals 1.8×10–5, then what is the pH of this solution? 
(log 1.8 = 0.25; log 0.67 = –0.176)

1.  9.43
2.  11.72
3.  8.73
4.  9.08

Subtopic:  Buffer |
 67%
Level 2: 60%+
AIPMT - 2011
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What conditions favor the formation of 2XY₄(g) in the reaction X₂(g) + 4Y₂(g) ⇋ 2XY₄(g), considering that the enthalpy change (ΔH) is negative?

1.  Low pressure and low temperature

2.  High temperature and low pressure

3.  High pressure and low temperature

4.  High temperature and high pressure

Subtopic:  Le Chatelier's principle |
 77%
Level 2: 60%+
AIPMT - 2011
Hints

For the reaction N2(g) + O2(g)2NO(g) the equilibrium constant is K1. The equilibrium constant is K2 for the reaction  2NO(g) + O2(g) 2NO2(g) 
The value of K for the reaction given below will be:
NO2(g)12N2(g) +O2(g) 

1.  14 4 K1 K2

2.  1K1K21/2

3.  1K1K2

4.  12K1K2

Subtopic:  Kp, Kc & Factors Affecting them |
 89%
Level 1: 80%+
AIPMT - 2011
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Calculate the hydrogen ion concentration, [\(\text{H}^+\)] (in \(\text{mol}/\text{L}\)), of a buffer solution prepared by mixing \(0.10 \text{ M}\) acetic acid (\(\text{CH}_3\text{COOH}\)) and \(0.20 \text{ M}\) sodium acetate (\(\text{CH}_3\text{COONa}\)), given that the acid dissociation constant (\(\text{K}_a\)) for acetic acid is \(1.8 \times 10^{-5}\):

1. \(3 . 5 \times 10^{- 4}\)
2. \(1 . 1 \times 10^{- 5}\)
3. \(1 . 8 \times 10^{- 5}\)
4. \(9 . 0 \times10^{- 6}\)

Subtopic:  Buffer |
 53%
Level 3: 35%-60%
AIPMT - 2010
Hints

The equilibrium reaction that doesn't have equal values for Kc and Kis: 

1. \(2NO(g) \rightleftharpoons N_2(g) + O_2(g)\)
2. \(SO_2(g) + NO_2(g) \rightleftharpoons SO_3(g) + NO(g)\)
3. \(H_2(g) + I_2(g) \rightleftharpoons 2HI (g)\)
4. \(2C(s) + O_2(g) \rightleftharpoons 2CO_2(g)\)

Subtopic:  Kp, Kc & Factors Affecting them |
 92%
Level 1: 80%+
AIPMT - 2010
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In a buffer solution containing an equal concentration of B- and HB, the Kb for B- is 10-10. pH of the buffer solution is:

1. 10 2. 7
3. 6 4. 4
Subtopic:  Buffer |
 72%
Level 2: 60%+
AIPMT - 2010
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Which of the following molecular hydrides acts as a Lewis acid?

1. NH3

2. H2O

3. B2H6

4. CH4

Subtopic:  Acids & Bases - Definitions & Classification |
 84%
Level 1: 80%+
AIPMT - 2010
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Which of the following molecules acts as a Lewis acid?
1. (CH3)3B
2. (CH3)2O
3. (CH3)3P
4. (CH3)3N
Subtopic:  Acids & Bases - Definitions & Classification |
 86%
Level 1: 80%+
AIPMT - 2009
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What is the [OH-] in the final solution prepared by mixing 20.0 mL of 0.050 M HCl with 30.0 mL of 0.10 M Ba(OH)2?

1. 0.10 M

2. 0.40 M

3. 0.0050 M

4. 0.12 M

Subtopic:  pH calculation |
 64%
Level 2: 60%+
AIPMT - 2009
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The dissociation constants for acetic acid and HCN at 25 °C are 1.5 x 10-5 and 4.5 x 10-10, respectively. The equilibrium constant for the equilibrium, 
CN- + CH3COOH  ⇌  HCN + CH3COO- 
would be:
1. 3.0×105
2. 3.0×10-5
3. 3.0×10-4
4. 3.0×104

Subtopic:  Kp, Kc & Factors Affecting them |
Level 3: 35%-60%
AIPMT - 2009
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