The geometry and magnetic behaviour of the complex [Ni(CO)4] are:
1. Square planar geometry and Diamagnetic
2. Tetrahedral geometry and Diamagnetic
3. Square planar geometry and Paramagnetic
4. Tetrahedral geometry and Paramagnetic

Subtopic:  VBT, CFT & their Limitations |
 60%
Level 2: 60%+
NEET - 2018
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Iron carbonyl, FeCO5, is classified as:

1. Tetranuclear 2. Mononuclear
3. Trinuclear 4. Dinuclear
Subtopic:  Organometallic Complexes & their Uses |
 79%
Level 2: 60%+
NEET - 2018
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Which of the following has the longest C ­—O bond length? (Free C—O bond length in CO is 1.128 Å)
1. [Co(CO)4]- 2. [Fe(CO)4]2-
3. Mn(CO)6]+ 4. Ni(CO)4
Subtopic:  VBT, CFT & their Limitations |
 79%
Level 2: 60%+
NEET - 2016
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The number of possible isomers for the complex Coen2Cl2Cl will be (en=ethylenediamine):

1. 2 2. 1
3. 3 4. 4
Subtopic:  Isomerism in Coordination Compounds |
 63%
Level 2: 60%+
NEET - 2015
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The hybridization involved in the complex NiCN42-is:
(Atomic number of Ni=28)

1. dsp2 2. sp3
3. d2sp2 4. d2sp3

Subtopic:  VBT, CFT & their Limitations |
 83%
Level 1: 80%+
NEET - 2015
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The sum of the coordination number and oxidation number of the metal M in the complex [M(en)2(C2O4)]Cl is:

1. 9 2. 6
3. 7 4. 8
Subtopic:  Introduction, Classification and Nomenclature |
 62%
Level 2: 60%+
NEET - 2015
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The IUPAC name of complex ion, [Fe(CN)6]3- is:

1. Hexacyanoiron(III) ion

2. Hexacyanitoferrate(III) ion

3. Tricynoferrate(III) ion

4. Hexacyanidoferrate(III) ion

Subtopic:  Introduction, Classification and Nomenclature |
 78%
Level 2: 60%+
NEET - 2015
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An ion, among the following, that has a magnetic moment of 2.84 BM is:
(At. no. Ni = 28, Ti = 22, Cr = 24, Co = 27)

1. Ni2+
2. Ti3+
3. Cr2+
4. Co2+

Subtopic:  VBT, CFT & their Limitations |
 81%
Level 1: 80%+
NEET - 2015
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Cobalt(III) chloride forms several octahedral complexes with ammonia.
A compound among the following that does not give a test for chloride ions with silver nitrate at 25 °C is:

1. CoCl3. 3NH3 2. CoCl3. 4NH3
3. CoCl3. 5NH3 4. CoCl3. 6NH3
Subtopic:  Introduction, Classification and Nomenclature |
 81%
Level 1: 80%+
NEET - 2015
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An anticancer agent among the following is:

1. \(\text { mer} - \left[\mathrm{Co}\left(\mathrm{NH}_3\right)_3 \mathrm{Cl}\right] \) 2. \(\text { cis -} \left[\mathrm{PtCl}_2\left(\mathrm{NH}_3\right)_2\right] \)
3. \(\text {cis -} \mathrm{K}_2\left[\mathrm{Pt} \mathrm{Cl}_2 \mathrm{Br}_2\right] \) 4. \(\mathrm{NH}_2 \mathrm{CoCl}_4\)
Subtopic:  Isomerism in Coordination Compounds |
 91%
Level 1: 80%+
AIPMT - 2014
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