Which of the following is the strongest acid?
1. HCOOH (pKa 3.77)
2. C6H5COOH (pKa 4.22)
3. CH3COOH (pKa 4.71)
4. CH3CH2COOH (pKa 4.88)
In this reaction,
CH3CHO + HCN CH3CH(OH)CN CH3CH(OH)COOH
an asymmetric compound is generated. The acid obtained would be
1. 50% D + 50% L-isomer
2. 20% D + 80% L-isomer
3. D-isomer
4. L-isomer
Ethane can be obtained from ethanal in one step by:
1. Na-Hg + water
2. Zn-Hg + conc.HCl
3. aluminium isopropoxide and isopropyl alcohol
4. LiAlH4 + ether
Cyanohydrin of which compound gives lactic acid on hydrolysis?
1. Acetone
2. Acetaldehyde
3. Propanal
4. HCHO
Which one of the following compounds on treatment with LiAlH4 will give a product that will give a positive iodoform test?
1. CH3CH2CHO
2. CH3CH2COOCH3
3. CH3CH2OCH2CH3
4. CH3COCH3
The IUPAC name of tartaric acid is:
1. 2,3-dihydroxy butane-1, 4-dioic acid
2. 1,4-dihydroxy butane-2-3-dioic acid
3. butane-1 4-dicarboxylic acid
4. none of the above
Oxalic acid on treatment with conc. H2SO4 gives:
1. CO + H2O2
2. H2O +CO+CO2
3. HCOOH + CO2
4. HCOOH + CO2 +O2
Aldehydes and ketones will not form crystalline derivatives with
1. sodium bisulphite
2. phenyl hydrazine
3. semicarbazide hydrochloride
4. dihydrogen sodium phosphate
Benzene sulphonic acid on treating with P2O5 gives:
1. salicylic acid
2. benzoic acid
3. acid anhydride
4. sodium benzoate
The IUPAC name of crotonaldehyde is:
1. But-2-en-1-al
2. Prop-2-enal
3. 4-Methylpent-3-en-2-one
4. None of the above