When d⁸ arrangement in nickel ion changes from a weak octahedral field in $\left[Ni\right(H_{2}O{)}_6{]}^{2\oplus }$ to a strong field in $\left[Ni\right(CN{)}_4{]}^{2⊝}$, which orbitals get lowered in energy? Assume tetragonal distortion along the Z-axis.

(1) $d_{x^2-y^2}$

(2) $d_{z^2}$

(3) $d_{xy} , d_{z^2}$

(4) $d_{xz} , d_{yz} , d_{z^2}$

The correct electronic configuration of Ti(Z=22 atom) is

(1) $1s^{2}2s^{2}2p^{6}3s^{2}3p^{6}3d^2$

(2) $1s^{2}2s^{2}2p^{6}3s^{2}3p^{6}3d^{2}4p^6$

(3) $1s^{2}2s^{2}2p^{6}3s^{2}3p^{6}3d^4$

(4) $1s^{2}2s^{2}2p^{6}3s^{2}3p^{6}4s^{2}3d^2$

Which of the following elements form stable dinuclear ions

1. Zn

2. Cd

3. Hg

4. Fe

When excess of SnCl₂ is added to HgCl₂, the substance formed is

1. Hg₂Cl₂

2. Sn

3. Hg

4. Cl₂

Heating of Ag with dil. HNO₃ give

1. NO

2. NO₂

3. N₂O

4. N₂O₃

Which of the following species has the highest number of unpaired electrons?

1. Fe²⁺

2. Fe³⁺

3. Co³⁺

4. Co²⁺

Which of the following pairs of compounds are more stable

(A) $K_2\left[NiC{l}_6\right],\left[Pt\right(CN{)}_4{]}^{2-}$

(B) NiCl₄, PtCl₄

(C) $\left[Ni\right(CN{)}_4{]}^{2-}, K_2\left[Pt\right(C{l}_6\left)\right]$

(D) PtCl₂, NiCl₂

Which one of the following statements is not correct

1. Nickel forms Ni(CO)₄

2. All the transition metals form mono-metallic carbonyls

3. Carbonyl are formed by transition metals

4. Transition metals form complexes

Which of the following products are formed when potassium bromide reacts with potassium permanganate in alkaline pH?

1. ${{\mathrm{BrO}}_3}^{‐}, {\mathrm{MnO}}_2$                                     

2. ${{\mathrm{BrO}}_4}^{‐}, {\mathrm{Mn}}^{2+}$

3. ${\mathrm{Br}}_2, {\mathrm{MnO}}_2$                                         

4. ${\mathrm{Br}}_2{\mathrm{O}}^{‐}, {{\mathrm{MnO}}_4}^{2‐}$

Select the correct statement :

(1) ${\mathrm{PH}}_3$ reduces ${\mathrm{AgNO}}_3$ to metallic Ag.

(2) Organic tissues turn ${\mathrm{AgNO}}_3$ black by reducing it to Ag.

(3) $\mathrm{AgCN}$is soluble in $\mathrm{KCN}$.

(4) All are correct statements.