The charge/size ratio of a cation determines its polarizing power. Which one of the following sequences represents the increasing order of the polarizing power of the cationic species, 

K+, Ca+2, Mg+2, Be+2

(1) Be+2<K+<Ca+2<Mg+2                     

(2) K+<Ca+2<Mg+2<Be+2

(3) Ca+2<Mg+2<Be+2<K+                     

(4) Mg+2<Be+2<K+<Ca+2

 

Subtopic:  Acidic, Basic Character & Fajan's Rule |
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The molecule having the smallest bond angle is-

1. PCl3 2. NCl3
3. AsCl3 4. SbCl3
Subtopic:  V.S.E.P.R & V.B.T |
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Which of the following statement is true for IO2F2-according to VSEPR theory?

(A) The lone pair and two I-O double bonds occupy the equatorial positions of trigonal
bipyramid.

(B) It has sp3 hybridization and is T-shaped.

(C)  Its structure is analogous to SF4.

(D) (A) and (C) both

Subtopic:  Hybridisation |
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No S-S bonds are present in?

1. \(S_{2}O_{3}^{2-}\)                                           

2. \(S_{2}O_{4}^{2-}\)

3. \(S_{2}O_{5}^{2-}\)                                                

4. \(S_{2}O_{7}^{2-}\)

Subtopic:  Group 16 - Preparation, Properties & Uses |
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A diatomic molecule has a dipole moment of 1.2 D. If its bond length is equal to 10 -10 m , then the fraction of an electronic charge on each atom will be:

1. 42%
2. 52%
3. 37%
4. 25%

Subtopic:  Polarity |
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Most covalent compound among the following is :

1. AlF3 2. AlCl3
3. AlBr3 4. AlI3
Subtopic:  Covalent Bond |
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The correct order of covalent bond character among
LiCl, BeCl2, BCl3 and CCl4, is:

1. LiCl < BeCl2 > BCl3 > CCl4

2. LiCl > BeCl2 < BCl3 < CCl4

3. LiCl < BeCl2 < BCl3 < CCl4

4. LiCl > BeCl2 > BCl3 > CCl4

Subtopic:  Covalent Bond |
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Which of the following conversions demonstrates an increase in bond order and a change in magnetic behaviour?

1. NONO+                                 

2. O2O2+

3. N2N2+                                   

4. C2C2+

Subtopic:  M.O.T |
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The ionisation energy will be maximum for the process:

(a) BaBa2+

(b) BeBe2+

(c) CsCs+

(d) LiLi+

Subtopic:  Ionization Energy (IE) |
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NF3 is:

(1) non-polar compound 

(2) electrovalent compound 

(3) having low value of dipole moment than NH3

(4) having more dipole moment than NH3

Subtopic:  Polarity |
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