At constant temperature, the equilibrium constant (Kp) for the decomposition reaction. N2O4 2NO2 is expressed by,
Kp = (4x2P)/(1-x2)
where P= pressure, x = extent of decomposition. Which of the following statements is true?
1. Kp increases with increase of P
2. Kp increases with increase of x
3. Kp increase with decrease of x
4. Kp remains constant with change in P of x
An aqueous solution of ammonium acetate is:
1. faintly acidic
2. fair acidic
3. faintly alkaline
4. almost neutral
For the reaction, A + B C+D, the initial concentration of A and B are equal, but the equilibrium concentration of C is twice that of the equilibrium concentration of A. The equilibrium constant is:
1. 4
2. 9
3. 1/4
4. 1/9
The hydroxide having the lowest value of Ksp at 25C is:
1. Mg(OH)2
2. Ca(OH)2
3. Ba(OH)2
4. Be(OH)2
The solubility product of CuS, CdS and HgS are 10-31, 10-44, 10-54 respectively. The solubility of these sulphides are in the order
1. CdS>HgS> CuS
2. HgS> CdS>CuS
3. CdS>CuS>HgS
4. CuS>CdS>HgS
The following equilibrium exists in an aqueous solution
CH3COOH H+ + CH3COO- . If dilute HCl is added to this solution:
1. the equilibrium constant will increase
2. the equilibrium constant will decrease
3. acetate ion concentration will increase
4. acetate ion concentration will decrease
Which can act as an acidic buffer?
| a. | NH4Cl + NH4OH |
| b. | CH3COOH + CH3COONa |
| c. | 40 mL of 0.1 M NaCN + 20 mL of 0.1 M HCl |
1. Both a and b
2. Both b, and c
3. All are buffer solution
4. Both a, and c
pH for the solution of salt undergoing anionic hydrolysis (say CH3COONa) is given by:
1. pH = [pKw + pKa + log c]
2. pH = [pKw + pKa - log c]
3. pH = [pKw + pKb - log c]
4. none of the above
The strongest acid among the following is:
1. H2SO4
2. HClO3
3. HClO4
4. H2SO3