Nitrogen gas is liberated by thermal decomposition of :

(1) ${\mathrm{NH}}_4{\mathrm{NO}}_2$                                 

(2) ${\mathrm{NaN}}_3$

(3) ${\left({\mathrm{NH}}_4\right)}_2{\mathrm{Cr}}_2{\mathrm{O}}_7$                           

(4) All    

Two oxides of nitrogen, $\mathrm{NO}$ and ${\mathrm{NO}}_2$ are allowed to react together at $243°<mspace\; width="1em"></mspace>\mathrm{K}$ and form a coloured compound of nitrogen (X). When compound (X) reacts with water to yield another compound of nitrogen (Y). The shape of the anion of (Y) molecule is :

(a) triangular planar                              (b) triangle pyramidal

(c) tetrahedron                                      (d) square planar 

Consider the following sequence of reaction.

$\mathrm{Na}+{\mathrm{NH}}_3\left(\mathrm{g}\right)\underset{}{\to }\left[\mathrm{X}\right]\stackrel{{\mathrm{N}}_2\mathrm{O}}{\to }\left[\mathrm{Y}\right]\stackrel{\mathrm{Heat}}{\to }\underset{\mathrm{Gas}<mspace\; width="1em"></mspace>\mathrm{Pure}}{\left[\mathrm{Z}\right]}$

Identify [Z] gas :

$\left(\mathrm{a}\right)<mspace\; width="1em"></mspace>{\mathrm{N}}_2$

$\left(\mathrm{b}\right)<mspace\; width="1em"></mspace>{\mathrm{NH}}_3$

$\left(\mathrm{c}\right)<mspace\; width="1em"></mspace>{\mathrm{O}}_2$

$\left(\mathrm{d}\right)<mspace\; width="1em"></mspace>{\mathrm{H}}_2$

Which of the following statements is true? 

Which of the following on heating produces ${\mathrm{NO}}_2$?

(a) ${\mathrm{NaNO}}_3$                               (b) ${\mathrm{AgNO}}_3$

(c) ${\mathrm{NH}}_4{\mathrm{NO}}_3$                              (d) ${\mathrm{NH}}_4{\mathrm{NO}}_2$

$\mathrm{A}+{\mathrm{H}}_2\mathrm{O}\stackrel{}{\to }\mathrm{B}+\mathrm{HCl}$
$\mathrm{B}+{\mathrm{H}}_2\mathrm{O}\stackrel{}{\to }\mathrm{C}+\mathrm{HCl}$

Compound (A),(B) and (C) will be respectively :

(a) ${\mathrm{PCl}}_5,<mspace\; width="1em"></mspace>{\mathrm{POCl}}_3,<mspace\; width="1em"></mspace>{\mathrm{H}}_3{\mathrm{PO}}_3$                 (b) ${\mathrm{PCl}}_5,<mspace\; width="1em"></mspace>{\mathrm{POCl}}_3,<mspace\; width="1em"></mspace>{\mathrm{H}}_3{\mathrm{PO}}_4$

(c) ${\mathrm{SOCl}}_2,<mspace\; width="1em"></mspace>{\mathrm{POCl}}_3,<mspace\; width="1em"></mspace>{\mathrm{H}}_3{\mathrm{PO}}_3$               (d) ${\mathrm{PCl}}_3,<mspace\; width="1em"></mspace>{\mathrm{POCl}}_3,<mspace\; width="1em"></mspace>{\mathrm{H}}_3{\mathrm{PO}}_4$

Which of the following is in the correct sequence?

[For the correct order mark (T) and for the incorrect order mark (F)]:

Incorrect statement regarding PH₃ is:

1. It is produced by the hydrolysis of Ca₃P₂${\mathrm{}}_{}$

2. It gives a black ppt, Cu₃P₂ with a CuSO₄ solution.

3. It spontaneously burns in the presence of ${\mathrm{P}}_2{\mathrm{H}}_4$

4. It does not react with ${\mathrm{B}}_2{\mathrm{H}}_6$

Which of the following compound does not produce oxyacid of central atom on hydrolysis?

(1) ${\mathrm{BF}}_3$                           

(2) ${\mathrm{NCl}}_3$

(3) ${\mathrm{SF}}_4$                           

(4) ${\mathrm{PCl}}_5$

The false statement regarding hydrides from the 15th group is: