Positronium is an unstable complex of electron and positron, both of the same mass, but opposite charge. Apply Bohr's theory of hydrogen atom to this system and obtain the energy required to separate the electron from the positron.

(ionization energy of the ground state hydrogen atom= 13.62eV.) Express the result in KJmol-1

(A) 550 KJmol-1

(B) 657 KJmol-1

(C) 851 KJmol-1

(D) 720 KJmol-1

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The total spin resulting from a d7 configuration is - 

(A) 3/2

(B) 1/2

(C) 2

(D) 1

Concept Questions :-

Quantum Numbers
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Supposing the energy of fourth shell for hydrogen atom is -50a.u. (Arbitrary unit). What would be its ionization potential-

(A) 50

(B) 800

(C) 15.4

(D) 20.8

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An element with atomic mass Z consists of two isotopes of mass number Z-1 and Z + 2. The percentage abundance of the heavier isotope is -

(A) 0.25

(B)33.3

(C)66.6

(D)75

Concept Questions :-

introduction
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Two isotopes of Boron are found in the nature with atomic weights 10.01(I) and 11.01(II). The atomic weight of natural Boron is 10.81. The percentage of (I) and (II) isotopes in it are respectively-

(A) 20 and 80

(B) 10 and 90

(C) 15 and 75

(D) 30 and 70

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introduction
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Calculate the wave-number  of lines having the frequency of 5 x 1016 cycles per sec. 

(A) 1.666 x 108m-1 

(B) 0.666 x 108m-1

(C) 4.126 x 106m-1

(D) 3.133 x 104m-1

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EMT Radiation
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Which of the following set of quantum number is not valid

(A) n = 1 , l = 2

(B) 3=2, m = 1

(C) m =3, l = 0

(D) 3 = 4, l = 2

Concept Questions :-

Quantum Numbers
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For particles having same kinetic energy, the de Broglie wavelength is-

(A) Directly proportional to its velocity

(B) Inversely proportional to its velocity

(C) Independent of velocity and mass

(D) Unpredictable

 

 

Concept Questions :-

de Broglie Equation
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Photochemical dissociation of oxygen results in the production of two oxygen atoms, one in the ground state and one in the excited state.

O2 hv O→O*

The maximum wavelength () needed for this is 174 nm. If the excitation energy O→O* is 3.15 x 10-19 J. How much energy in kJ mole-1 is needed for the dissociation of one mole of oxygen into normal atoms in ground state?

(A) 498.3 kJ mol-1

(B) 418.3 kJ mol-1

(C) 524.1 kJ mol-1

(D) 612.8 kJ mol-1

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Rutherford's scattering experiment is related to the size of the-

(A) Nucleus

(B) Atom

(C) Electron

(D) Neutron

Concept Questions :-

Rutherford's Experiment
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