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The incorrect order of ionic size among the following is :

(1)La3+>Gd3+>Eu3+>Lu3+           (2)V2+>V3+>V4+>V5+

(3) Tl+>In+>Sn2+>Sb3+                (4)K+>Sc3+>V5+>Mn7+

Subtopic:  Atomic Size |
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Consider the following changes:

 M(s)M(g).....(i)
M(s)M2+(g)+2e-.....(ii)
M(g)M+(g)+e-.....(iiii)
M+(g)M2+(g)+e-......(iv)
M(g)M2+(g)+2e-......(v)

The second ionization energy of M could be calculated from the energy values associated with :

(a) 1+3+4                  (b) 2-1+3

(c) 1+5                      (d) 5-3

Subtopic:  Ionization Energy (IE) |
Level 3: 35%-60%
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Which of the following statements is incorrect?

1. Van der Waals' radius of iodine is more than its covalent radius.
2. All isoelectronic ions belong to the same period of the periodic table.
3. I.E1 of the nitrogen atom is higher than that of the oxygen atom, while I.E2 of the oxygen atom is higher than that of the nitrogen atom.
4. The electron affinity of the nitrogen atom is almost zero while that of the phosphorus atom is 74.3 kJ mol-1
Subtopic:   Evolution of Periodic Table |
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Aqueous solutions of two compounds M1-O-HandM2-O-H are prepared in two different beakers. If, the electronegativity of M1=3.4,M2=1.2,O=3.5andH=2.1, then the nature of two solutions will be respectively:

(a) acidic, basic             (b) acidic, acidic

(c) basic, acidic             (d) basic, basic

Subtopic:  Electronegativity |
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First three ionisation energies (in kJ/mol) of three representative elements are given below:

Element     IE1                    IE2                   IE3

P               495.8                4562                  6910
Q               737.7               1451                   7733
R               577.5                1817                  2745

Then incorrect option is :

1. Q: Alkaline earth metal.

2. P: Alkali metal.

3. R: s-block element.

4. All three: P,Q & R belong to the same period.

Subtopic:  Ionization Energy (IE) |
Level 3: 35%-60%
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If the ionization enthalpy and negative electron gain enthalpy of an element are 275 and 86 kcal mol-1 respectively, then the electronegativity of the element on the Pauling scale is:

1. 2.8                                     

2. 0.0

3. 4.0                                     

4. 2.6

Subtopic:  Ionization Energy (IE) |
Level 3: 35%-60%
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The incorrect statement is:

(1) The second ionisation energy of Se is greater than that of second ionisation energy of As 

(2) The first ionisation energy of C2+ ion is greater than that of first ionisation energy of N2+ ion

(3) The third ionisation energy of F is greater than that of third ionisation energy of O

(4) Helogens have highest I.E. in respective period

Subtopic:  Ionization Energy (IE) |
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Consider the following ionisation reactions :

I.E. (kJ mol-1)

AgAg++e-,A1
B(g)+B(g)2++e-,B2
C(g)+C(g)2++e-,C2
B(g)B(g)++e-,B1
C(g)C(g)++e-,C1
C(g)2+C(g)3++e-,C3

If monovalent positive ion of A, divalent positive ion of B and trivalent positive ion of C have zero electron. Then incorrect order of corresponding I.E. is :

(1) C3>C2>B2                       

(2) B1>A1>C1

(3) C3>C2>B2                       

(4) B2>C3>A1

Subtopic:  Ionization Energy (IE) |
Level 3: 35%-60%
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The incorrect match among the following options is:

1.

\([Ar]3d^54s^1 \rightarrow 4^{th} \text {period}, 6^{th} \text {group}\)

2. \([Kr]4d^{10} \rightarrow 5^{th} \text {period}, 12^{th} \text {group}\)
3. \([Rn]6d^2 7s^2\rightarrow 7^{th} \text {period}, 3^{rd} \text {group}\)
4. \([Xe]4f^{14} 5d^26s^2 \rightarrow 6^{th} \text {period}, 4^{th} \text {group}\)
Subtopic:  Electronic Configuration |
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Which of the following order is correct for the property mentioned in brackets?

(a)S2->Cl->K+>Ca2+                 (Ionisation energy)

(b)C<N<F<O                              (2nd Ionisation energy)

(c)B>Al>Ga>In>Tl                     (Electronegativity)

(d)Na+>Li+>Mg2+>Be2+>Al3+    (Ionic radius)

Subtopic:  Ionization Energy (IE) |
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