| Statement I: | The boiling point of hydrides of Group 16 elements follow the order \(\text{H}_2 \text{O}>\text{H}_2 \text{Te}>\text{H}_2 \text{Se}>\text{H}_2 \text{S} .\) |
| Statement II: | On the basis of molecular mass, H2O is expected to have lower boiling point than the other members of the group but due to the presence of extensive H-bonding in H2O, it has higher boiling point. |
| 1. | Se | 2. | Te |
| 3. | Po | 4. | O |
| List-I (Oxoacids of Sulphur) |
List-II (Bonds) |
||
| A. | Peroxodisulphuric acid | I. | Two S-OH, Four S=O, One S-O-S |
| B. | Sulphuric acid | II. | Two S-OH, One S=O |
| C. | Pyrosulphuric acid | III. | Two S-OH, Four S=O, One S-O-O-S |
| D. | Sulphurous acid | IV. | Two S-OH, Two S=O |
| Options: | A | B | C | D |
| 1. | III | IV | II | I |
| 2. | I | III | II | IV |
| 3. | III | IV | I | II |
| 4. | I | III | IV | II |
| (a) | F–F bond has a low enthalpy of dissociation. |
| (b) | Flouride ion (F–) has high hydration enthalpy. |
| (c) | Electron gain enthalpy of fluorine is less negative than chlorine. |
| (d) | Fluorine has a very small size. |
| 1. | (a) and (b) only | 2. | (a) and (c) only |
| 3. | (a) and (d) only | 4. | (b) and (c) only |
| 1. | \(\mathrm{NaNO}_3+\mathrm{H}_2 \mathrm{SO}_4\xrightarrow[500~K, \ 9\text{ bar}]{Pt} \mathrm{NaHSO}_4+\mathrm{HNO}_3\) |
| 2. | \(4 \mathrm{NH}_3+5 \mathrm{O}_2 \text{(from air)}\xrightarrow[500~K, \ 9\text{ bar}]{Pt} 4 \mathrm{NO}+6 \mathrm{H}_2 \mathrm{O}\) |
| 3. | \(4 \mathrm{HPO}_3+2 \mathrm{~N}_2 \mathrm{O}_5\xrightarrow[500~K, \ 9\text{ bar}]{Pt} 4 \mathrm{HNO}_3+\mathrm{P}_4 \mathrm{O}_{10}\) |
| 4. | \(\mathrm{Cu}\left(\mathrm{NO}_3\right)_2+2 \mathrm{NO}_2+2 \mathrm{H}_2 \mathrm{O} \\ \xrightarrow[500~K, \ 9\text{ bar}]{Pt} 4 \mathrm{HNO}_3+\mathrm{Cu}\) |
Chlorine shows the bleaching action in the presence of moisture due to the formation of
1. HOCl
2. HOClO
3. H2O2
4. Atomic oxygen
The correct order for boiling points of the following compounds is:
| 1. | AsH3 > PH3 > NH3 > SbH3 > BiH3 |
| 2. | BiH3 > SbH3 > NH3 > AsH3 > PH3 |
| 3. | NH3 > PH3 > AsH3 > SbH3 > BiH3 |
| 4. | PH3 > NH3 > AsH3 > SbH3 > BiH3 |
| Statement I: | The boiling points of the following hydrides of group 16 elements increase in the order \(\mathrm{H}_{2} \mathrm{O}<\mathrm{H}_{2} \mathrm{~S}<\mathrm{H}_{2} \mathrm{Se}<\mathrm{H}_{2} \mathrm{Te} \) |
| Statement II: | The boiling points of these hydrides increase with the increase in molar mass. |
| Assertion (A): | ICl is more reactive than I₂. |
| Reason (R): | I-Cl bond is weaker than I-I bond. |
| 1. | (A) is False but (R) is True. |
| 2. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
| 3. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
| 4. | (A) is True but (R) is False. |
| 1. | It is a radioactive substance. |
| 2. | It is a very stable substance. |
| 3. | Half-life of Radon is longer. |
| 4. | It forms variety of compounds. |