List-I (Complex) | List-II (Type of isomerism) | ||
A. | \(\mathrm{\left[{Co}\left({NH}_3\right)_5\left({NO}_2\right)\right] {Cl}_2}\) | I. | Solvate isomerism |
B. | \(\mathrm{\left[{Co}\left({NH}_3\right)_5\left({SO}_4\right)\right] {Br}}\) | II. | Linkage isomerism |
C. | \(\mathrm{\left[{Co}\left({NH}_3\right)_6\right]\left[{Cr}({CN})_6\right]}\) | III. | Ionization isomerism |
D. | \(\mathrm{\left[{Co}\left({H}_2 {O}\right)_6\right] {Cl}_3}\) | IV. | Coordination isomerism |
Statement I: | \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+}\) is a homoleptic complex, whereas \([Co(NH_3)_4 Cl_2]^+\) is a heteroleptic complex. |
Statement II: | Complex \([Co(NH_3)_6]^{3+}\) has only one kind of ligand but \([Co(NH_3)_4 Cl_2]^+\) has more than one kind of ligands. |
1. | Hexadentate ligand | 2. | Ambidentate ligand |
3. | Monodentate ligand | 4. | Bidentate ligand |
1. | Chlorodifluoridoethylenediaminechromium(III) chloride |
2. | Bis-(ethylenediamine)difluoridochromium(III) chloride |
3. | Difluorobis-(ethylenediamine)chromium(III) chloride |
4. | Chlorodifluoridobis(ethylenediamine)chromium (III) |
A. | Carnallite (KCl.MgCl2.6H2O) is an example of double salt. |
B. | Thiocyanato ligand behaves as an ambidentate ligand. |
C. | [CoF6]3- is called a spin-free complex. |
1. | A and B | 2. | B and C |
3. | A and C | 4. | A, B, and C |
List-I (Complexes) | List-II (Type of isomer) | ||
A. | [Co(NH3)5NO2]Cl2 and [Co(NH3)5ONO]Cl2 | I. | Ionisation isomerism |
B. | [Cr(NH3)6] [Co(CN)6] and [Cr(CN)6][Co(NH3)6] | II. | Coordination isomerism |
C. | [Co(NH3)5(SO4)]Br and [Co(NH3)5Br]SO4 | III. | Linkage isomerism |
D. | [Cr(H2O)6]Cl3 and [Cr(H2O)5Cl]Cl2.H2O | IV. | Solvate isomerism |
(A) | (B) | (C) | (D) | |
1. | (III) | (I) | (II) | (IV) |
2. | (II) | (III) | (IV) | (I) |
3. | (III) | (II) | (I) | (IV) |
4. | (IV) | (III) | (II) | (I) |