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Match the complexes from List-I with their corresponding type of isomerism from List-II:
List-I (Complex) List-II (Type of isomerism)
A. \(\mathrm{\left[{Co}\left({NH}_3\right)_5\left({NO}_2\right)\right] {Cl}_2}\) I. Solvate isomerism
B. \(\mathrm{\left[{Co}\left({NH}_3\right)_5\left({SO}_4\right)\right] {Br}}\) II. Linkage isomerism
C. \(\mathrm{\left[{Co}\left({NH}_3\right)_6\right]\left[{Cr}({CN})_6\right]}\) III. Ionization isomerism
D. \(\mathrm{\left[{Co}\left({H}_2 {O}\right)_6\right] {Cl}_3}\) IV. Coordination isomerism

Choose the correct from the options given below:

1. A-I, B-III, C-IV, D-II
2. A-I, B-IV, C-III, D-II
3. A-II, B-IV, C-III, D-I
4. A-II, B-III, C-IV, D-I

Subtopic:  Isomerism in Coordination Compounds |
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Given below are two statements : 
Statement I:  \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+}\) is a homoleptic complex, whereas \([Co(NH_3)_4 Cl_2]^+\) is a heteroleptic complex.
Statement II: Complex \([Co(NH_3)_6]^{3+}\) has only one kind of ligand but \([Co(NH_3)_4 Cl_2]^+\) has more than one kind of ligands. 
In light of the above statements, choose the correct answer from the options given below:
1. Both Statement I and Statement II are False.
2. Statement I is True but Statement II is False.
3. Statement I is false but Statement II is True.
4. Both Statement I and Statement II are True.
Subtopic:  Introduction, Classification and Nomenclature |
 85%
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NEET - 2024
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Ethylene diaminetetraacetate ion is a/an :
1. Hexadentate ligand 2. Ambidentate ligand
3. Monodentate ligand 4. Bidentate ligand
Subtopic:  Ligands |
 80%
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NEET - 2024
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Which of the following is not an ambidentate ligand?
1. \(\mathrm{C_2O^{2-}_4}\)
2. \(\mathrm{SCN}^-\)
3. \(\mathrm{NO^{-}_2}\)
4. \(\mathrm{CN}^-\)
Subtopic:  Ligands |
 82%
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NEET - 2024
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Type of isomerism exhibited by compounds
[Cr(H2O)6]Cl3, [Cr(H2O)5Cl]Cl2.H2O,
[Cr(H2O)4Cl2]Cl.2H2O and the value of coordination number (CN) of central metal ion in all these compounds, respectively, is:
1. Geometrical isomerism, CN = 2
2. Optical isomerism, CN = 4
3. Ionisation isomerism, CN = 4
4. Solvate isomerism, CN = 6
Subtopic:  Isomerism in Coordination Compounds |
 85%
From NCERT
NEET - 2023
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A pink-colored cobalt complex, denoted as (X), exists in aqueous solution. Upon reacting with concentrated HCl, it forms a deep blue-colored complex (Y). What are the identities of (X) and (Y), and what is the geometry of complex (Y), denoted as (Z)?

1. \(\left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+},\left[\mathrm{CoCl}_6\right]^{3-}, \text {Octahedral} \)  
2. \(\left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{3+},\left[\mathrm{CoCl}_4\right]^{2-}, \text {Tetrahedral} \)
3. \(\left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+},\left[\mathrm{CoCl}_4\right]^{2-}, \text {Tetrahedral } \)
4. \(\left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{3+},\left[\mathrm{CoCl}_6\right]^{3-}, \text {Octahedral} \)
Subtopic:  VBT, CFT & their Limitations |
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A diamagnetic compound among the following is:

1. [Co(F6)]3–
2. [Ni(CN)4]2–
3. [NiCl4]2–
4. [Fe(CN)6]3–
Subtopic:  VBT, CFT & their Limitations |
 81%
From NCERT
NEET - 2013
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The correct IUPAC name for [CrF2(en)2]Cl is:
 
1. Chlorodifluoridoethylenediaminechromium(III) chloride
2. Bis-(ethylenediamine)difluoridochromium(III) chloride
3. Difluorobis-(ethylenediamine)chromium(III) chloride
4. Chlorodifluoridobis(ethylenediamine)chromium (III)
Subtopic:  Introduction, Classification and Nomenclature |
 81%
From NCERT
NEET - 2013
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Consider the following statements:
A. Carnallite (KCl.MgCl2.6H2O) is an example of double salt.
B. Thiocyanato ligand behaves as an ambidentate ligand.
C. [CoF6]3- is called a spin-free complex.
Which of the above statements are correct?
1. A and B 2. B and C
3. A and C 4. A, B, and C
Subtopic:  Introduction, Classification and Nomenclature |
 54%
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Match List-I with List-II :
List-I (Complexes) List-II (Type of isomer)
A. [Co(NH3)5NO2]Cl2 and [Co(NH3)5ONO]Cl2 I. Ionisation isomerism
B. [Cr(NH3)6] [Co(CN)6] and [Cr(CN)6][Co(NH3)6] II. Coordination isomerism
C. [Co(NH3)5(SO4)]Br and [Co(NH3)5Br]SO4 III. Linkage isomerism
D. [Cr(H2O)6]Cl3 and [Cr(H2O)5Cl]Cl2.H2O IV. Solvate isomerism
Choose the correct answer from the options given below:
(A) (B) (C) (D)
1. (III) (I) (II) (IV)
2. (II) (III) (IV) (I)
3. (III) (II) (I) (IV)
4. (IV) (III) (II) (I)
Subtopic:  Isomerism in Coordination Compounds |
 87%
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NEET - 2022
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