Osmotic pressure is 0.0821 atm at a temperature of 300 K. Find concentration in mole/litre [Roorkee 1990]

(1) 0.033

(2) 0.066

(3) 0.33 × 10–2

(4) 3

Subtopic:  Osmosis & Osmotic Pressure |
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The osmotic pressure of 5 % (mass-volume) solution of cane sugar at 150 °C (mol. mass of sugar = 342 g/mole) is:

1. 4 atm 2. 5.07 atm
3. 3.55 atm 4. 2.45 atm
Subtopic:  Osmosis & Osmotic Pressure |
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A solution containing 3.3 g of a substance in 125 g of benzene (b.p. 80°C) boils at 80.66°C. If Kb for one litre of benzene is 3.28°C, the molecular weight of the substance shall be 

1. 127.20

2. 131.20

3. 137.12

4. 142.72

Subtopic:  Elevation of Boiling Point |
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The molal b.p. constant for water is 0.513oCkgmol1. When 0.1 mole of sugar is dissolved in 200 g of water, the solution boils under a pressure of 1 atm at

(1) 100.513°C

(2) 100.0513°C

(3) 100.256°C

(4) 101.025°C

Subtopic:  Elevation of Boiling Point |
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An aqueous solution containing 1 g of urea boils at 100.25 °C. The aqueous solution containing 3 g of glucose in the same volume will boil at:
1. 100.75 °C
2. 100.5 °C
3. 100 °C
4. 100.25 °C

Subtopic:  Osmosis & Osmotic Pressure |
 73%
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Solution of sucrose (Mol. Mass = 342) is prepared by dissolving 34.2 gm of it in 1000 gm of water. Freezing point of the solution is (Kf for water is 1.86 K kg mol–1) [AIEEE 2003]

(1) 272.814 K

(2) 278.1 K

(3) 273.15 K

(4) 270 K

Subtopic:  Depression of Freezing Point |
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An aqueous solution of a weak monobasic acid containing 0.1 g in 21.7 g of water freezes at 272.817K. If the value of Kf for water is 1.86 K kg mol–1, the molecular mass of the acid is [AMU 2002]

(1) 46.0

(2) 48.6

(3) 48.8

(4) 46.8

Subtopic:  Depression of Freezing Point |
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What is the molality of the solution of a certain solute in a solvent if there is a freezing point depression of 0.184° and if the freezing point constant is 18.4 K kg 

1. 0.01

2. 1.00

3. 0.001

4. 100

Subtopic:  Depression of Freezing Point |
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A solution containing 6.8 g of a non-ionic solute in 100 g of water was found to freeze at −0.93 oC. The freezing point depression constant of water is 1.86. The molecular weight of the solute is-

1. 13.6 m 2. 34 m
3. 68 m 4. 136 m
Subtopic:  Depression of Freezing Point |
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The molar freezing point constant for water is 1.86°C/mole. If 342 g of cane sugar (C12H22O11) is dissolved in 1000 g of water, the solution will freeze at 

1. –1.86°C

2. 1.86°C

3. –3.92°C

4. 2.42°C

Subtopic:  Depression of Freezing Point |
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