Consider the following reaction,

$\mathrm{Phenol}\stackrel{\mathrm{Zn}<mspace\; width="1em"></mspace>\mathrm{dust}}{\to }\mathrm{X}\underset{\mathrm{Anhydrous}<mspace\; width="1em"></mspace>{\mathrm{AlCl}}_3}{\overset{{\mathrm{CH}}_3\mathrm{Cl}}{\to }}\mathrm{Y}\stackrel{\mathrm{Alkaline}<mspace\; width="1em"></mspace>{\mathrm{KMnO}}_4}{\to }\mathrm{Z},$

the product, Z, is

1. toluene

2. benzaldehyde

3. benzoic acid

4. benzene

Aniline in a set of the following reactions yielded a coloured product 'Y'.

The structure of 'Y' would be

Which one of the following on reduction with lithium aluminium hydride yields a secondary amine?

(1) nitroethane

(2) methylisocyanide

(3) acetamide

(4) methylcyanide

The reaction of toluene with Cl₂ in presence of FeCl₃ gives 'X' and reaction in presence of

light gives 'Y'. Thus, 'X' and 'Y' are

1. X = Benzal chloride, Y = o-chlorotoluene

2. X = m-chlorotoluene, Y= p-chlorotoluene

3. X = o-and p-chlorotoluene, Y=trichloromethyl benzene

4. X = Benzyl chloride, Y = m-chlorotoluene

Acetamide is treated with the following reagents separately. Which one of these would

yield methyl amine?

1. NaOH-Br₂

2. Sodalime

3. Hot conc. H₂SO₄

4. PCl₅

Predict the product C obtained in the following reaction of butyne-1.

$C{H}_{3}C{H}_2-C\equiv CH+HCl\to B\stackrel{HI}{\to }<mspace\; width="1em"></mspace>C$

1. $C{H}_3-\underset{\underset{Cl}{|}}{C}H-C{H}_{2}C{H}_{2}I$

2. $C{H}_3-C{H}_2-C{H}_2-\underset{\underset{Cl}{|}}{\overset{\stackrel{I}{|}}{C}}-H$

3. ${\mathrm{CH}}_3-{\mathrm{CH}}_2-\stackrel{\stackrel{\mathrm{I}}{|}}{\mathrm{C}}\mathrm{H}-{\mathrm{CH}}_2\mathrm{Cl}$

4. ${\mathrm{CH}}_3{\mathrm{CH}}_2-\underset{\underset{\mathrm{Cl}}{|}}{\overset{\stackrel{\mathrm{I}}{|}}{\mathrm{C}}}-{\mathrm{CH}}_3$

In a set of reactions, ethyl benzene yielded a product D.

Which one is a nucleophilic substitution reaction among the following?

1.
2.
3.	\(\mathrm{CH}_3 \mathrm{CHO}+\mathrm{HCN} \rightarrow \mathrm{CH}_3 \mathrm{CH}(\mathrm{OH}) \mathrm{CN}\)
4.

Consider the following reaction,

the product Z is:

1. CH₂=CH₂

2. CH₃CH₂-O-CH₂-CH₃

3. CH₃-CH₂-O-SO₃H

4. CH₃CH₂OH