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For a given reaction, if ΔH = 35.5 kJ/mol and ΔS = 83.6 J/K·mol, at what temperature is the reaction spontaneous?
(Assume ΔH and ΔS remain constant with temperature.)

1. T < 425 K 2. T > 425 K
3. All temperatures 4. T > 298 K

Subtopic:  Gibbs Energy Change |
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A gas is allowed to expand in a well insulated container against a constant external pressure of 2.5 atm from an initial volume of 2.50 L to a final volume of 4.50 L. The change in internal energy U of the gas in joules will be

(1) 1136.25 J

(2) - 500 J

(3) - 505 J

(4) + 515 J

Subtopic:  First Law of Thermodynamics |
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For a given reaction, ∆H = 35.5 kJ mol–1 and ∆S = 83.6 J K–1 mol–1. The reaction is spontaneous at:
[Note: Assume that ∆H and ∆S  do not vary with temperature]

1. T > 425K
2. All temperatures
3. T > 298K
4. T < 425K

Subtopic:  Gibbs Energy Change |
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NEET - 2017
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A gas is allowed to expand in a well-insulated container against a constant external pressure of 2.5atm from an initial volume of 2.50 L to a final volume of 4.50L. The change in internal energy U of the gas in joules will be:

1. –500J 2. –505J
3. –506J 4. –508J
Subtopic:  First Law of Thermodynamics |
Level 3: 35%-60%
NEET - 2017
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The correct thermodynamic conditions for a spontaneous reaction at all temperatures is:
1. H > 0 and S< 0
2. H < 0 and S> 0
3. H < 0 and S< 0
4. H > 0 and S = 0
Subtopic:  Gibbs Energy Change |
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NEET - 2016
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The heat of combustion of carbon to CO2 is –393.5 KJ/mol. The heat released upon the formation of 35.2 g of CO2 from carbon and oxygen gas is:
1. –315 KJ
2. +315 KJ
3. –630 KJ
4. +630 KJ

Subtopic:  Thermochemistry |
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NEET - 2015
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The correct statement for a reversible process in a state of equilibrium is:
1. G = – 2.30RT log K
2. G = 2.30RT log K
3. Go = – 2.30RT log K
4. Go = 2.30RT log K

Subtopic:  Gibbs Energy Change |
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NEET - 2015
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What is the value of \(\mathrm{K_{sp}}\) of \(\mathrm {Ag_2CO_3 (s) }\) in water at 25º C for the following reaction; 
\(\mathrm{Ag_2 CO_3 (s) \rightarrow 2Ag^+ (aq) + CO^{2-}_3 (aq)}\)

[Given: \(\text R = 8.314 \text J\text K^{–1} \text {mol}^{–1}\) \(\Delta \text G^\circ=+63.3~\text{kJ}\) ]

1. \(3.2 \times 10^{26}\)
2. \(8.0 \times 10^{-12}\)
3. \(2.9 \times 10^{-3}\)
4. \(7.9 \times 10^{-2}\)
Subtopic:  Gibbs Energy Change |
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Level 2: 60%+
AIPMT - 2014
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For the reaction:
\(\mathrm{X}_2 \mathrm{O}_4(l) \rightarrow 2 \mathrm{XO}_2(g)\)
with the given values \(\Delta U = 2.1 \, \text{kcal}\) and \(\Delta S = 20 \, \text{cal K}^{-1}\) at \(300 \, \text{K}\), what is the value of \(\Delta G\)?

1. +2.7 kcal
2. –2.7 kcal
3. +9.3 kcal
4. –9.3 kcal

Subtopic:  Gibbs Energy Change |
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AIPMT - 2014
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In which of the following reactions, the standard reaction entropy change
(S0) is positive, and standard Gibb's energy change
(G0) decreases sharply with increasing temperature?

1. C(graphite) + \(\frac{1}{2}\)O2(g) → CO(g)
2. CO(g) + \(\frac{1}{2}\)O2(g) → CO2(g)
3. Mg(s) + \(\frac{1}{2}\)O2(g) → MgO(s)
4. \(\frac{1}{2}\)C(graphite) + \(\frac{1}{2}\)O2(g) → \(\frac{1}{2}\)CO2(g)

Subtopic:  Gibbs Energy Change |
 71%
Level 2: 60%+
AIPMT - 2012
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