The correct order of nucleophilicity among the following is:

(I) CH3COO-

(II) CH3CO-

(III) CN-

(IV) 

1. I > II > III > IV

2. IV > III > II > I

3. II > III > I > IV

4. III > II > I > IV

Subtopic:  Nucleophile & Electrophile |
Level 4: Below 35%
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The compound which gives the most stable carbocation on dehydration:

1.CH3-CH-(CH3)-CH2OH

2. CH3-C(CH3)2-OH

3. CH3 - CH2 - CH2 - CH2OH

4.CH3-CH(OH)-CH2-CH3

Subtopic:  Reaction Intermediates ; Preparation & Properties |
 73%
Level 2: 60%+
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Allyl isocyanide has:

1. 9 σ, and 4π-bonds.

2. 8 σ, and 5π-bonds

3. 9 σ, and 3π-bonds, 

4. 8 σ, and 3 π bonds

Subtopic:  Hybridisation & Structure of Carbon Compounds |
 67%
Level 2: 60%+
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Which of the following acids has the smallest dissociation constant?

(1) CH3CHFCOOH

(2) FCH2CH2COOH

(3) BrCH2CH2COOH

(4) CH3CHBrCOOH

Subtopic:  Acidic & Basic Character |
 64%
Level 2: 60%+
Hints

Which of the following resonating structures of 1-methoxy-1,3-butadiene is least stable?

1. \(\stackrel{\ominus}{\mathrm{C}} \mathrm{H}_2-\mathrm{CH}=\mathrm{CH}-\mathrm{CH}=\stackrel{\oplus}{\mathrm{O}}-\mathrm{CH}_3\)
2. \(C H_2=\mathrm{CH}_2-\stackrel{\ominus}{\mathrm{C}} \mathrm{H}-\mathrm{CH}=\stackrel{\oplus}{\mathrm{O}}-\mathrm{CH}_3\)
3. \(\stackrel{\ominus}{\mathrm{C}} \mathrm{H}_2-\stackrel{\oplus}{\mathrm{C}} \mathrm{H}-\mathrm{CH}=\mathrm{CH}-\mathrm{O}-\mathrm{CH}_3\)
4. \(\mathrm{CH}_2=\mathrm{CH}-\stackrel{\ominus}{\mathrm{C}} \mathrm{H}-\stackrel{\oplus}{\mathrm{C}} \mathrm{H}-\mathrm{O}-\mathrm{CH}_3\)

Subtopic:  Electron Displacement Effects |
Level 3: 35%-60%
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The IUPAC name of the compound shown below is:

1. 2-bromo-6-chlorocyclohex-1-ene

2. 6-bromo-6-chlorocyclohexene

3. 3-bromo-1-chlorocyclohex-1-ene

4. 1-bromo-3-chlorocyclohexene

Subtopic:  Nomenclature |
 89%
Level 1: 80%+
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Which of the following structures are superimposable?

(1) 

(2) 

(3) 

(4) 

(1) 1 and 2

(2) 2 and 3

(3) 1 and 4

(4) 1 and 3

 

 

 

 

 

Subtopic:  Stereo Isomers |
Level 3: 35%-60%
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The production of an optically active compound from a symmetric molecule without resolution in termed as:

(1) Walden inversion

(2) partial racemisation

(3) asymmetric synthesis

(4) partial resolution

Subtopic:  Stereo Isomers |
Level 3: 35%-60%
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Find the type of isomerism shown by buta-1,3-diene and but-2-yne.

1. Position isomers

2. Functional isomers

3. Chain isomers

4. Tautomers

Subtopic:  Structural Isomers |
 77%
Level 2: 60%+
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Find the number of different substitution products possible when ethane reacts with chlorine
in the presence of sunlight.
 

1. Nine (9)
2. Six (6)
3. Eight (8)
4. Five (5)
Subtopic:  Structural Isomers |
Level 3: 35%-60%
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