Allyl isocyanide has:

1. 9 σ, and 4π-bonds.

2. 8 σ, and 5π-bonds

3. 9 σ, and 3π-bonds, 

4. 8 σ, and 3 π bonds

Subtopic:  Hybridisation & Structure of Carbon Compounds |
 67%
Level 2: 60%+
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Which of the following acids has the smallest dissociation constant?

(1) CH3CHFCOOH

(2) FCH2CH2COOH

(3) BrCH2CH2COOH

(4) CH3CHBrCOOH

Subtopic:  Acidic & Basic Character |
 64%
Level 2: 60%+
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Which of the following resonating structures of 1-methoxy-1,3-butadiene is least stable?

1. \(\stackrel{\ominus}{\mathrm{C}} \mathrm{H}_2-\mathrm{CH}=\mathrm{CH}-\mathrm{CH}=\stackrel{\oplus}{\mathrm{O}}-\mathrm{CH}_3\)
2. \(C H_2=\mathrm{CH}_2-\stackrel{\ominus}{\mathrm{C}} \mathrm{H}-\mathrm{CH}=\stackrel{\oplus}{\mathrm{O}}-\mathrm{CH}_3\)
3. \(\stackrel{\ominus}{\mathrm{C}} \mathrm{H}_2-\stackrel{\oplus}{\mathrm{C}} \mathrm{H}-\mathrm{CH}=\mathrm{CH}-\mathrm{O}-\mathrm{CH}_3\)
4. \(\mathrm{CH}_2=\mathrm{CH}-\stackrel{\ominus}{\mathrm{C}} \mathrm{H}-\stackrel{\oplus}{\mathrm{C}} \mathrm{H}-\mathrm{O}-\mathrm{CH}_3\)

Subtopic:  Electron Displacement Effects |
Level 3: 35%-60%
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The IUPAC name of the compound shown below is:

1. 2-bromo-6-chlorocyclohex-1-ene

2. 6-bromo-6-chlorocyclohexene

3. 3-bromo-1-chlorocyclohex-1-ene

4. 1-bromo-3-chlorocyclohexene

Subtopic:  Nomenclature |
 89%
Level 1: 80%+
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Which of the following structures are superimposable?

(1) 

(2) 

(3) 

(4) 

(1) 1 and 2

(2) 2 and 3

(3) 1 and 4

(4) 1 and 3

 

 

 

 

 

Subtopic:  Stereo Isomers |
Level 3: 35%-60%
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The production of an optically active compound from a symmetric molecule without resolution in termed as:

(1) Walden inversion

(2) partial racemisation

(3) asymmetric synthesis

(4) partial resolution

Subtopic:  Stereo Isomers |
Level 3: 35%-60%
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Find the type of isomerism shown by buta-1,3-diene and but-2-yne.

1. Position isomers

2. Functional isomers

3. Chain isomers

4. Tautomers

Subtopic:  Structural Isomers |
 77%
Level 2: 60%+
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Find the number of different substitution products possible when ethane reacts with chlorine
in the presence of sunlight.
 

1. Nine (9)
2. Six (6)
3. Eight (8)
4. Five (5)
Subtopic:  Structural Isomers |
Level 3: 35%-60%
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In butane, which of the following forms has the lowest energy?

(1) Gauche form

(2) Eclipsed form

(3) Staggered form

(4) None of these

Subtopic:  Conformational Isomers |
 67%
Level 2: 60%+
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Diastereomers can be separated by:

1. Fractional distillation

2. simple distillation

3. electrophoresis

4. all of these

Subtopic:  Stereo Isomers |
 58%
Level 3: 35%-60%
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