Allyl isocyanide has:
1. 9 σ, and 4π-bonds.
2. 8 σ, and 5π-bonds
3. 9 σ, and 3π-bonds,
4. 8 σ, and 3 π bonds
Which of the following acids has the smallest dissociation constant?
(1) CH3CHFCOOH
(2) FCH2CH2COOH
(3) BrCH2CH2COOH
(4) CH3CHBrCOOH
Which of the following resonating structures of 1-methoxy-1,3-butadiene is least stable?
1. \(\stackrel{\ominus}{\mathrm{C}} \mathrm{H}_2-\mathrm{CH}=\mathrm{CH}-\mathrm{CH}=\stackrel{\oplus}{\mathrm{O}}-\mathrm{CH}_3\)
2. \(C H_2=\mathrm{CH}_2-\stackrel{\ominus}{\mathrm{C}} \mathrm{H}-\mathrm{CH}=\stackrel{\oplus}{\mathrm{O}}-\mathrm{CH}_3\)
3. \(\stackrel{\ominus}{\mathrm{C}} \mathrm{H}_2-\stackrel{\oplus}{\mathrm{C}} \mathrm{H}-\mathrm{CH}=\mathrm{CH}-\mathrm{O}-\mathrm{CH}_3\)
4. \(\mathrm{CH}_2=\mathrm{CH}-\stackrel{\ominus}{\mathrm{C}} \mathrm{H}-\stackrel{\oplus}{\mathrm{C}} \mathrm{H}-\mathrm{O}-\mathrm{CH}_3\)
The IUPAC name of the compound shown below is:
1. 2-bromo-6-chlorocyclohex-1-ene
2. 6-bromo-6-chlorocyclohexene
3. 3-bromo-1-chlorocyclohex-1-ene
4. 1-bromo-3-chlorocyclohexene
Which of the following structures are superimposable?
(1)
(2)
(3)
(4)
(1) 1 and 2
(2) 2 and 3
(3) 1 and 4
(4) 1 and 3
The production of an optically active compound from a symmetric molecule without resolution in termed as:
(1) Walden inversion
(2) partial racemisation
(3) asymmetric synthesis
(4) partial resolution
Find the type of isomerism shown by buta-1,3-diene and but-2-yne.
1. Position isomers
2. Functional isomers
3. Chain isomers
4. Tautomers
Find the number of different substitution products possible when ethane reacts with chlorine
in the presence of sunlight.
In butane, which of the following forms has the lowest energy?
(1) Gauche form
(2) Eclipsed form
(3) Staggered form
(4) None of these
Diastereomers can be separated by:
1. Fractional distillation
2. simple distillation
3. electrophoresis
4. all of these