Which is the major product expected from the following S_N² reaction?

1.      

2.     

3.     

4.    

Arrange the following alkyl bromides in decreasing order of their rate of E2 elimination under identical conditions:

(a)
(b)
(c)

Compare rate of E₂ reaction:-
1. c>b>a

2. a>b>c

3. b>a>c

4. c>a>b
           

Which is the major product of the following reaction?

 $\underset{H_{2}O}{\overset{}{\to }}$
$heatNaOH<mspace\; width="1em"></mspace>Product$

1. 

2. 

3. 

4. 

1-2-dichloro ethane + NaSCH₂CH₂SNa $\to$ P (C₄H₈S₂) 

Unknown product (p) of the above reaction is:

1. 

2. 

3. $\mathrm{H}-\mathrm{S}-\mathrm{CH}=\mathrm{CH}-\mathrm{CH}=\mathrm{CH}-\mathrm{S}-\mathrm{H}$

4. $\mathrm{H}-\mathrm{CH}=\mathrm{CH}-{\mathrm{CH}}_2-\mathrm{S}-\mathrm{H}$

$\stackrel{\mathrm{Moist}<mspace\; width="1em"></mspace>{\mathrm{Ag}}_2\mathrm{O}}{\to }$ (A) product

Major product (A) is:

1.  

2. 

3. 

4. 

 $\stackrel{\mathrm{KCN}}{\to }$  Product of reaction is:

 (MOM chloride)

(Methoxy methyl chloride)

1. 

2. 

3.  $Me-O-C{H}_2-C{H}_2-CN<mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace>$

4. $CN<mspace\; width="1em"></mspace>-C{H}_2-CN<mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace>$

Alkyl halides can be obtained by all methods except:

1. ${\mathrm{CH}}_3{\mathrm{CH}}_2\mathrm{OH}<mspace\; width="1em"></mspace>+\hspace{0.17em}\mathrm{HCl}/{\mathrm{ZnCl}}_2<mspace\; width="1em"></mspace>\stackrel{<mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace>}{\to }$

2. ${\mathrm{CH}}_3-{\mathrm{CH}}_2-{\mathrm{CH}}_3-{\mathrm{CH}}_2<mspace\; width="1em"></mspace>\stackrel{{\mathrm{Cl}}_2/\mathrm{UV}<mspace\; width="1em"></mspace>\mathrm{light}}{\to }$

3. ${\mathrm{C}}_2{\mathrm{H}}_5\mathrm{OH}<mspace\; width="1em"></mspace>+\hspace{0.17em}\mathrm{NaCl}<mspace\; width="1em"></mspace>\stackrel{<mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace>}{\to }$

4. ${\mathrm{CH}}_3\mathrm{COOAg}<mspace\; width="1em"></mspace>+<mspace\; width="1em"></mspace>{\mathrm{Br}}_2/{\mathrm{CCl}}_4<mspace\; width="1em"></mspace>\stackrel{<mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace>}{\to }$

In order to prepare 1-chloropropane, which of the following reactants can be employed?
(1) Propane and HCl in the presence of peroxide

(2) Propene and Cl₂ followed by treatment with aq. KOH

(3) Propanol-1 and SOCl₂/pyridine

(4) Any of the above can be used

Which of the following molecules would have a carbon-halogen bond most susceptible to nucleophilic substitution ?

(1) 2-Fluorobutane

(2) 2-Chlorobutane

(3) 2-Bromobutane

(4) 2-Iodobutane

When benzyl chloride is treated with ethanolic KCN, the major product formed is:-
(1) benzyl ethyl ether

(2) benzyl alcohol

(3) benzyl cyanide

(4) benzyl isocyanide