\(\mathrm{CH_3-CH_3, \ CH_3-CH_2-CH_3, \ }\)
\(\mathrm{\left(CH_3\right)_2 CH-CH_3, }\) and \(\mathrm{CH_3-CH_2-CH\left(CH_3\right)_2 }\)
The increasing order of stability of the free radicals formed from homolytic fission of the above three alkanes is:
| 1. | \(\mathrm{ (CH_3)_2 \dot{C}-CH_2 CH_3<CH_3-\dot{C} H-CH_3 \\ <CH_3-\dot{C} H_2<(CH_3)_3 \dot{C} }\) |
| 2. | \( \mathrm{CH_3-\dot{C} H_2<CH_3-\dot{C} H-CH_3 \\ <\left(CH_3\right)_2 \dot{C}-CH_2 CH_3<\left(CH_3\right)_3 \dot{C}}\) |
| 3. | \(\mathrm{CH_3-\dot{C} H_2<CH_3-\dot{C} H-CH_3\\ <\left(CH_3\right)_3 \dot{C}<\left(CH_3\right)_2 \dot{C}-CH_2 CH_3 }\) |
| 4. | \(\mathrm{ \left(CH_3\right)_3 \dot{C}<\left(CH_3\right)_2 \dot{C}-CH_2-CH_3 \\ <CH_3-\dot{C} H-CH_3<CH_3-\dot{C} H_2 }\) |
| 1. | 2. | ||
| 3. | 4. |
| 1. | ![]() |
| 2. | |
| 3. | |
| 4. | ![]() |
| 1. | 2. | ||
| 3. | 4. |
| 1. | sp2 | 2. | spd2 |
| 3. | sp2d | 4. | sp3 |
| List-I (Mixtures/Sample) |
List-II (Technique used for purification) |
||
| A. | Glycerol from spent lye | (I) | Steam distillation |
| B. | Chloroform + Aniline | (II) | Fractional distillation |
| C. | Fractions of crude oil | (III) | Distillation under reduced pressure |
| D. | Aniline+water | (IV) | Distillation |
| Options: | (A) | (B) | (C) | (D) |
| 1. | III | IV | II | I |
| 2. | IV | II | I | III |
| 3. | I | II | III | IV |
| 4. | I | III | II | IV |