Amongst the following, which one will have maximum 'lone pair - lone pair' electron repulsions? 

1. \(XeF_2\)
2. \(CIF_3\)
3. \(IF_5\)
4. \(SF_4\)

Subtopic:  V.S.E.P.R & V.B.T |
 74%
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Which one of the following statements is true about the structure of \(CO^{2-}_3\) ion?

1. It can be explained by considering sp3 hybridization.
2. Out of the three C–O bonds, two are longer and one is shorter.
3. It has three Sigma and three \(\pi\)-bonds.
4. All three C–O bonds are equal in length with a bond order in between 1 and 2.
Subtopic:  Resonance & Nature of Compounds |
 53%
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Which one of the following is the correct order of decreasing bond enthalpies for the given species?

1. \(O^{2-}_2>O^-_2>O_2>N_2 \) 2. \(N_2>O_2>O^{2-}_2>O^-_2 \)
3. \(N_2>O_2>O^-_2>O^{2-}_2 \) 4. \(O_2>N_2>O^-_2>O^{2-}_2 \)
Subtopic:  M.O.T |
 71%
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The correct order of bond angles in the following compounds/species is:

1.  \(\mathrm{H}_2 \mathrm{O}<\mathrm{NH}_3<\mathrm{NH}_4^{+}<\mathrm{CO}_2 \)
2.  \(\mathrm{H}_2 \mathrm{O}<\mathrm{NH}_4^{+}<\mathrm{NH}_3<\mathrm{CO}_2 \)
3.  \(\mathrm{H}_2 \mathrm{O}<\mathrm{NH}_4^{+}=\mathrm{NH}_3<\mathrm{CO}_2 \)
4.  \(\mathrm{CO}_2<\mathrm{NH}_3<\mathrm{H}_2 \mathrm{O}<\mathrm{NH}_4^{+} \)
Subtopic:  V.S.E.P.R & V.B.T |
 66%
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Match List-I with List-II :
List-I
(Molecules)
List-II
(Shape)
(a) NH3 (i) Square pyramidal
(b) ClF3 (ii) Trigonal bipyramidal
(c) PCl5 (iii) Trigonal pyramidal
(d) BrF5 (iv) T-shape
Choose the correct answer from the options given below:
(a) (b) (c) (d)
1. (ii) (iii) (iv) (i)
2. (iii) (iv) (ii) (i)
3. (iv) (iii) (i) (ii)
4. (iii) (iv) (i) (ii)
Subtopic:  V.S.E.P.R & V.B.T |
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Identify incorrect the statement among the following options:
 
1.  \(O^+_2\) ion is diamagnetic.
2. The bond orders of \(O_2^{+},O_2,O^-_2\) and \(O_2^{2-}\) are 2.5, 2, 1.5, and 1, respectively.
3.  \(C_2\) molecule has four electrons in its two degenerate \(\pi \) molecular orbitals.
4.  \(H^+_2 \) ion has one electron.
Subtopic:  M.O.T |
 78%
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The correct order of energies of molecular orbitals of N2 molecule is:
1. \( \sigma \text { 1s }<\sigma^* \text { 1s }<\sigma 2 s<\)
\(\sigma^* 2 s<\left(\pi 2 p_x=\pi 2 p_y\right)<\)
\(\left(\pi^* 2 p_x=\pi^* 2 p_y\right)<\sigma 2 p_z<\sigma^* 2 p_z\)
2. \( \sigma \text { 1s }<\sigma^* \text { 1s }<\sigma 2 s<\sigma^* 2 s<\)
\(\left(\pi 2 p_x=\pi 2 p_y\right)< \)
\(\sigma 2 p_z<\left(\pi^* 2 p_x=\pi^* 2 p_y\right)<\sigma^* 2 p_z \)
3. \( \sigma \text { 1s }<\sigma^* \text { 1s }<\sigma 2 s<\sigma^* 2 s<\sigma 2 p_z<\)
\( \left(\pi 2 p_x=\pi 2 p_y\right)<\)
\(\left(\pi^* 2 p_x=\pi^* 2 p_y\right)<\sigma^* 2 p_z \)
4. \( \sigma \text { 1s }<\sigma^* \text { 1s }\)
\(<\sigma 2 s<\sigma^* 2 s<\sigma 2 p_z< \)
\( \sigma^* 2 p_z<\left(\pi 2 p_x=\pi 2 p_y\right)<\)
\(\left(\pi^* 2 p_x=\pi^* 2 p_y\right) \)
Subtopic:  M.O.T |
 70%
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Given the following five species:
 \(\mathrm{NH}_3, \mathrm{AlCl}_3, \mathrm{BeCl}_2, \mathrm{CCl}_4, \mathrm{PCl}_5 \)
The total number of these species that do not have eight electrons around the central atom in its/their outermost shell, is/are:
1. 1 2. 3
3. 2 4. 4
Subtopic:  Octate, Isoelectronic Species, Lewis Structure & Formal Charge |
 57%
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NEET - 2023
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The correct order of dipole moments for molecules \(NH_3, H_2S , CH_4 \) and \(HF\) is : 
1. \(CH_4>H_2S>NH_3>HF \)   
2. \(H_2S>NH_3>HF>CH_4 \)
3. \(NH_3>HF>CH_4>H_2~S \)
4. \(HF>NH_3>H_2S>CH_4\)
Subtopic:  Polarity |
 65%
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Which one of the following represents all isoelectronic species? 

1. \(Na^+ , Cl^-, O^- , NO^+\)
2. \(N_2O, N_2O_4 , NO^+, NO\)
3. \(Na^+ , Mg^{2+} , O^- , F^-\)
4. \(Ca^{2+} , Ar, K^+, Cl^-\)
Subtopic:  Octate, Isoelectronic Species, Lewis Structure & Formal Charge |
 75%
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