If $∆{\mathrm{H}}_{\mathrm{f}}^{°}$(C₂H₄) and $∆{\mathrm{H}}_{\mathrm{f}}^{°}$(C₂H₆) are x₁ and x₂ kcal/mol then heat of hydrogenation of C₂H₄ is :-

(1) x₁ + x₂

(2) x₁ - x₂

(3) x₂ - x₁

(4) x₁ + 2x₂

For given following equations and $∆\mathrm{H}°$ values, determine the enthalpy of reaction at 298 K for the reaction 

C₂H₄(g) + 6F₂(g) $\to$ 2CF₄(g) + 4HF(g)

H₂(g) + F₂(g) $\to$ 2HF(g)       $∆{\mathrm{H}}_1^{°}$= -537 kJ

C(s) + 2F₂(g) $\to$CF₄(g)         $∆{\mathrm{H}}_2^{°}$=-680 kJ

2C(s) + 2H₂(g) $\to$C₂H₄(g)    $∆{\mathrm{H}}_3^{°}$= 52 kJ

1. -1165 

2. -2486

3. +1165

4. +2486

Which of the following reactions has/have a positive \(\Delta S\) (entropy change)?

(i) Ag⁺ (aq) + Cl^-(aq) $\to$AgCl(s)

(ii) NH₄Cl(g) $\to$NH₃(g) + HCl(g)

(iii) 2NH₃(g)$\to$N₂(g) + 3H₂(g)

1. (i) & (ii)

2. (iii)

3. (ii) & (iii)

4. (ii)

Warming ammonium chloride with sodium hydroxide in a test tube is an example of:

1. closed system

2. Isolated system

3. open system

4. None of these

For the reaction, X₂O₄(l) $\to$2XO₂(g)

$∆$U = 2.1 kcal, $∆$S = 20 cal K^-1 at 300 K. Hence, $∆$G is

1. 2.7 kcal

2. -2.7 kcal

3. 9.3 kcal

4. -9.3 kcal

The enthalpy of fusion of water is 1.435 kcal/mol. The molar entropy change for the melting of ice at 0 °C is:

1. 10.52 cal/(mol K)

2. 21.04 cal/(mol K)

3. 5.260 cal/(mol K)

4. 0.526 cal/(mol K)

The enthalpy and entropy change for the reaction :

Br₂ (l) + Cl₂ (g)$\to$ 2BrCl (g)

are 30 kJ mol^-1 and 105 J K^-1 mol^-1 respectively.

The temperature at which the reaction will be in equilibrium is :

The temperature of the system decreases in an

(1) Adiabatic compression

(2) Isothermal compression

(3) Isothermal expansion

(4) Adiabatic expansion

Mark the correct statement 

1. For a chemical reaction to be feasible, ΔG should be zero

2. Entropy is a measure of order in a system

3. For a chemical reaction to be feasible, ΔG should be positive

4. The total energy of an isolated system is constant

Which of the following is not a state function 

(1) Internal energy

(2) Enthalpy

(3) Work

(4) Entropy