A metal ion present in vitamin B12 is:

1. Fe(II) 2. Co(III)
3. Zn(II) 4. Ca(II)

Subtopic:  Organometallic Complexes & their Uses |
 79%
Level 2: 60%+
AIPMT - 2003
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The coordination number of Ni in [Ni(C2O4)3]4- is:

1. 3 2. 6
3. 4.
Subtopic:  Introduction, Classification and Nomenclature |
 82%
Level 1: 80%+
AIPMT - 2001
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The organometallic compound that is σ and π bonded is:

1. [Fe(η5-C5H5)2]

2. K[PtCl3(η2-C2H4)]

3. [Co(CO)5NH3]+2

4. Fe(CH3)3

Subtopic:  Organometallic Complexes & their Uses |
 61%
Level 2: 60%+
AIPMT - 2001
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The incorrect option among the following is:

1. Ni(CO)4, Tetrahedral, paramagnetic
2. [Ni(CN)4]2-, Square planar, diamagnetic
3. Ni(CO)4, Tetrahedral, diamagnetic
4. [Ni(Cl)4]2-, Tetrahedral, paramagnetic

Subtopic:  VBT, CFT & their Limitations |
 76%
Level 2: 60%+
AIPMT - 2001
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The complex that will exhibit maximum ionic conductivity in aqueous solution is:

1. K4[Fe(CN)6]

2. [Co(NH3)6]Cl3

3. [Cu(NH3)4]Cl2

4. [Ni(CO)4]

Subtopic:  Introduction, Classification and Nomenclature |
 69%
Level 2: 60%+
AIPMT - 2001
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FeSO4 solution mixed with (NH4)2SO4 solution in 1:1 molar ratio gives the test of Fe2+ ion but CuSO4 solution mixed with aqueous ammonia in 1:4 molar ratio does not give the test of Cu2+ ion because:

1. The former is an example of a basic compound, while the latter is an amphoteric compound
2. The former is an example of an amphoteric compound, while the latter is a basic compound
3. The former is an example of a double salt, while the latter is a coordination compound
4. The former is an example of a coordination compound, while the latter is a double salt

Subtopic:  Introduction, Classification and Nomenclature |
 73%
Level 2: 60%+
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The oxidation number and coordination number of Co in [Co(H2O)(CN)(en)2]2+respectively are:    

1. 3, 6

2. 3, 2

3. 2, 2

4. 1, 3

Subtopic:  Introduction, Classification and Nomenclature |
 87%
Level 1: 80%+
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Total number of optical isomers [Pt(NH3)(Br)(Cl)(py)] can show:

1. 3

2. 2

3. 1

4. 0

Subtopic:  Introduction, Classification and Nomenclature |
Level 3: 35%-60%
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The difference between a weak field ligand and a strong field ligand is:

1. Weak field ligands cause higher splitting in the d orbitals than strong field ligands.
2. Weak field ligands cause lower splitting in the d orbitals than strong field ligands.
3. Strong field ligands do not form a complex with a metal ion.
4. None of the above.

Subtopic:  VBT, CFT & their Limitations |
 68%
Level 2: 60%+
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The crystal field splitting energy is:

1. The heat of formation between the two levels (e and t2) in tetrahedral splitting
2. The total pairing energy of the two levels (e and t2) in tetrahedral splitting.
3. The sum of the energy levels in an octahedral crystal field splitting.
4. The combined energy of the two levels (eg and t2g) in octahedral splitting.

Subtopic:  VBT, CFT & their Limitations |
 60%
Level 2: 60%+
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