In which case rate of diffusion is highest if all are present in the same container at the same temerature:
1. 4g H2
2. 32g O2
3. 22g CO2
4. 56g N2
At high pressure, Vander Waal gas equation is reduced to (For 1 mole of gas)
1. Z = 1- a/RTV
2. PV = RT +Pb
3. PV = RT +a/V
4. Z = 1- Pb/RT
Partial pressure of Hydrogen in a flask containing 2 gm of H2 and 32 gm of SO2 is:
1. 1/16 of total pressure
2. 1/2 of total pressure
3. 2/3 of total pressure
4. 1/8 of total pressure
At high pressure, the compressibility factor 'Z' is equal to-
1. Unity
2. 1-
3. 1+
4. Zero
At constant temperature, 200 cm3 of N2 at 720 mm and 400 cm3 of O2 at 750 mm pressure are put together in a one-litre flask. The final pressure of the mixture is-
1. 111 mm
2. 222 mm
3. 333 mm
4. 444 mm
The rate of diffusion of two gases A and B is in the ratio of 1:4 and the B and C in the ratio 1:3 the rate of diffusion of C with respect to A is
1. 1/12
2. 12
3. 3
4. 4
A sample of air contains only N2, O2 and H2O. It is saturated with water vapours and the total pressure of 640 torr. The vapoure pressure of water is 40 torr and the molar ratio of N2:O2 is 3:1. The partial pressure of N2 in the sample in
1. 480 torr
2. 600 torr
3. 525 torr
4. 450 torr
The temperature at which the r.m.s velocity of carbon dioxide becomes the same as that of nitrogen at 210C is-
1. 462 oC
2. 273 K
3. 189 oC
4. 546 K
At what temperature will the total K.E. of 0.3 mol of He be the same as the total K.E. of 0.4 mol of Ar at 400 K
1. 400K
2. 300K
3. 346K
4. 533K
The density of O2(g) is maximum at-
1. STP
2. 273 K and 2 atm
3. 546 K and 1 atm
4. 546 K and 2 atm