If 8 g of a non-electrolyte solute is dissolved in 114 g of n-octane to reduce its vapor pressure to 80 %, the molar mass (in g mol–1) of the solute is -
[Molar mass of n-octane is 114 g mol–1]
1. | 40 | 2. | 60 |
3. | 80 | 4. | 20 |
Isotonic solutions have the same:
1. Vapour pressure
2. Freezing temperature
3. Osmotic pressure
4. Boiling temperature
The molarity of H2SO4 solution that has a density 1.84 g/cc at 35 oC and contains 98 % H2SO4 by weight is-
1. | 1.84 M | 2. | 81.4 M |
3. | 18.4 M | 4. | 184 M |
Vapour pressure of chloroform \(\mathrm{(CHCl_3)}\) and dichloromethane \(\mathrm{(CH_2Cl_2)}\) at are 200 mmHg and 41.5 mmHg respectively. Vapour pressure of the solution was obtained by mixing 25.5 g of \(\mathrm{(CHCl_3)}\) and 40 g of \(\mathrm{(CH_2Cl_2)}\) at the same temperature will be: (Molecular mass of \(\mathrm{(CHCl_3)}\) = 119.5 u and molecular mass of \(\mathrm{(CH_2Cl_2)}\) = 85 u)
1. | 90.40 mm Hg | 2. | 119.5 mm Hg |
3. | 75 mm Hg | 4. | 173.9 mm Hg |
A 0.1 molal aqueous solution of a weak acid (HA) is 30 % ionized. If Kf for water is 1.86 °C/m, the freezing point of the solution will be:
1. | –0.24 °C | 2. | –0.18 °C |
3. | –0.54 °C | 4. | –0.36 °C |
200 mL of an aqueous solution contains 1.26 g of protein. The osmotic pressure of this solution at 300 K is found to be 2.57 × 10–3 bar. The molar mass of protein will be:
(R = 0.083 L bar mol–1 K–1):
1. | 61038 g mol–1 | 2. | 51022 g mol–1 |
3. | 122044 g mol–1 | 4. | 31011 g mol–1 |
Henry’s law constant for the molality of methane in benzene at 298 K is 4.27 × 105 mm Hg. The solubility of methane in benzene at 298 K under 760 mm Hg is -
1. 1.78 x 10-3
2. 1.78 x 10-5
3. 2.98 x 10-4
4. 3.78 x 10-3
The addition of water vapour does not change the density of:
1. CCl4
2. CS2
3. Ether
4. Coke
1 % (w/w) solution of a compound is isotonic with 5 % (w/w) sucrose (sugar) solution. The molecular weight of the compound will be:
1. | 32.4 | 2. | 68.4 |
3. | 129.6 | 4. | 34.2 |
The vapour pressure of a solvent decreased by 10 mm of Hg when a non-volatile solute was added to the solvent. The mole fraction of the solute in solution is 0.2. What would be the mole fraction of the solvent if the decrease in vapour pressure is 20 mm of Hg:
1. 0.2
2. 0.4
3. 0.6
4 0.8