If for a certain reaction ${∆}_{r}H$ is 30 kJ mol^–1 at 450 K, the value of ${∆}_{r}S$ (in JK^–1 mol^–1) for which the same reaction will be spontaneous at the same temperature is:

1.	70	2.	–33
3.	33	4.	–70

At standard conditions, if the change in the enthalpy for the following reaction is –109 kJ mol^–1 
H_2(g)+Br_2(g)$\to$2HBr_(g) and the bond energy of H₂ and Br₂ is 435 kJ mol^–1 and 192 kJ mol^–1 respectively, what is the bond energy (in kJ mol^–1) of HBr?

For the reaction, 2Cl(g) $\to$ Cl₂(g), the correct option is:

1. ${∆}_{\mathrm{r}}\mathrm{H}>0 \mathrm{and} {∆}_{\mathrm{r}}\mathrm{S}<0$

2. ${∆}_{\mathrm{r}}\mathrm{H}<0 \mathrm{and} {∆}_{\mathrm{r}}\mathrm{S}>0$

3. ${∆}_{\mathrm{r}}\mathrm{H}<0 \mathrm{and} {∆}_{\mathrm{r}}\mathrm{S}<0$

4. ${∆}_{\mathrm{r}}\mathrm{H}>0 \mathrm{and} {∆}_{\mathrm{r}}\mathrm{S}>0$

Hydrolysis of sucrose is given by the following reaction

Sucrose + H₂O $\rightleftharpoons$ Glucose + Fructose

If the equilibrium constant (K_c) is 2$\times$10¹³ at 300 K, the value of ${∆}_r{G}^{⊝}$ at the same temperature will be:

1. 8.314 J mol^–1 K^–1$\times$300 K$\times$ln (2$\times$10¹³)

2. 8.314 J mol^–1 K^–1$\times$300 K$\times$ln (3$\times$10¹³)

3. –8.314 J mol^–1 K^–1$\times$300 K$\times$ln (4$\times$10¹³)

4. –8.314 J mol^–1 K^–1$\times$300 K$\times$ln (2$\times$10¹³)

Reversible expansion of an ideal gas under isothermal and adiabatic conditions are as shown in the figure:

 

AB$\to$Isothermal expansion

AC$\to$Adiabatic expansion

Which of the following options is not correct?

1. $∆S_{isothermal}>∆S_{adiabatic}$

2. $T_A=T_B$

3. $W_{isothermal}>W_{adiabatic}$

4. $T_C>T_A$

An ideal gas expands isothermally from ${10}^{-3}{m}^3 to {10}^{-2} m^3$ at 300 K against a constant pressure of ${10}^5 N{m}^{-2}$. The work done by  the gas is:

A process among the following shows decrease in entropy is :

1. \(2 \text H \left(g\right)\rightarrow\text H_{2} \left(g\right)\)

2. Evaporation of water

3. Expansion of a gas at a constant temperature

4. Sublimation of solid to gas

Under the isothermal condition, a gas at \(300 \mathrm{~K}\) expands from \(0.1 \mathrm{~L}\) to \(0.25 \mathrm{~L}\) against a constant external pressure of 2 bar. The work done by the gas is:
1. \(30 ~\mathrm {J} \)
2. \(-30 ~\mathrm{J} \)
3. \(5~ \mathrm{kJ}\)
4. \(25~ \mathrm{J}\)

Assuming each reaction is carried out in an open container,
Reaction that shows ΔH=ΔE is :

1. $H_2\left(g\right)+B{r}_2\left(g\right)\to 2HBr\left(g\right)$

2. $C\left(s\right)+2H_{2}O\left(g\right)\to 2H_2\left(g\right)+C{O}_2\left(g\right)$

3. $PC{l}_5\left(g\right)\to PC{l}_3\left(g\right)+C{l}_2\left(g\right)$

4. $2CO\left(g\right)+O_2\left(g\right)\to 2C{O}_2\left(g\right)$