Assertion (A):	Toluene on Friedel Crafts methylation gives o- and p- xylene.
Reason (R):	$C{H}_3$ -group bonded to benzene ring increases electron density at o- and p- position.

  

1.	Both (A) and (R) are True and (R) is the correct explanation of (A).
2.	Both (A) and (R) are True and (R) is not the correct explanation of (A).
3.	(A) is True but (R) is False.
4.	(A) is False but (R) is True.

Given below are two statements: 

Match the reactions given in Column-I with the type of reaction given in Column-II and mark the appropriate option:

Codes:

Match the hydrocarbons in Column I with the boiling points given in Column II.

Codes

Which of the following is a free radical substitution reaction?

1. Benzene with Br₂/AlCl₃

2. Acetylene with HBr

3. Methane with Br₂/hv

4. Propene with HBr/(C₆H₅COO)₂

The products of ozonolysis of 1,2-dimethyl benzene (o-xylene) are:

1. Methylglyoxal, 1, 2-dimethylglyoxal, and glyoxal

2. Methylglyoxal, 1, 3-dimethylglyoxal, and glyoxal

3. Methylglyoxal, 1, 4-dimethylglyoxal, and glyoxal

4. Methylglyoxal, 1, 5-dimethylglyoxal, and glyoxal

The correct order of decreasing reactivity of the following compounds:

Chlorobenzene, 2,4-Dinitrochlorobenzene, and p-Nitrochlorobenzene

with an electrophile (E⁺)  is :

Out of the above alkenes, the ones that can give 2-methyl butane on hydrogenation are:

$\mathrm{Ethyne} \stackrel{?}{\to }$ $\mathrm{Benzene}$ 

The reagent used in the above conversion is:

1. Cr₂O₃

2. Alc. KOH

3. Red hot Fe

4. NaNH₂/liq.NH₃