Select the correct option based on statements below:

Assertion (A): Phosphorus chlorides (tri and Penta) are preferred over thionyl chloride for the preparation of alkyl chlorides from alcohols.
Reason (R): Phosphorus chlorides give pure alkyl halides.
 
1. Both (A) and (R) are true and (R) is the correct explanation of (A).
2. Both (A) and (R) are true but (R) is not the correct explanation of (A).
3. (A) is true but (R) is false.
4. Both (A) and (R) are false.

Subtopic:  Chemical Properties |
 69%
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Select the correct option based on statements below:

Assertion (A): The boiling points of alkyl halides decrease in the order RI> RBr > RCl > RF
Reason (R): The boiling points of alkyl chlorides, bromides, and iodides are considerably higher than those of the hydrocarbons of comparable molecular mass.
 
1. Both (A) and (R) are true and (R) is the correct explanation of (A).
2. Both (A) and (R) are true but (R) is not the correct explanation of (A).
3. (A) is true but (R) is false.
4. (A) is false but (R) is true.
Subtopic:  Introduction and Physical Properties |
 59%
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Select the correct option based on statements below:

Assertion (A): KCN reacts with methyl chloride to give methyl isocyanide.
Reason (R): \(CN^-\) is an ambident nucleophile.
 
1. Both (A) and (R) are true and (R) is the correct explanation of (A).
2. Both (A) and (R) are true but (R) is not the correct explanation of (A).
3. (A) is true but (R) is false.
4. (A) is false but (R) is true.

Subtopic:  Chemical Properties |
 71%
From NCERT
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Select the correct option based on statements below:

Assertion (A): The presence of a nitro group at ortho or para position increases the reactivity of haloarenes towards nucleophilic substitution.
Reason (R): The nitro group, being an electron-withdrawing group, decreases the electron density over the benzene ring.
 
1. Both (A) and (R) are True and (R) is the correct explanation of (A).
2. Both (A) and (R) are True but (R) is not the correct explanation of (A).
3. (A) is True but (R) is False.
4. (A) is False but (R) is True.
Subtopic:  Haloarenes: Directive Influence of Halogen |
 81%
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Select the correct option based on statements below:

Assertion (A): It is difficult to replace chlorine with -OH in chlorobenzene in comparison to that in chloroethane.
Reason (R): Chlorine carbon (—Cl) bond in chlorobenzene has a partial double bond character due to resonance.
 
1. Both (A) and (R) are true and (R) is the correct explanation of (A).
2. Both (A) and (R) are true but (R) is not the correct explanation of (A).
3. (A) is true but (R) is false.
4. (A) is false but (R) is true.
Subtopic:  Haloarenes: Directive Influence of Halogen |
 90%
From NCERT
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 Sulphuric acid is not used during the reaction of alcohols with KI and acts as :

1. Reducing agent

2. Electron donor

3. Electron acceptor

4. Oxidising agent

Subtopic:  Mechanism of Reactions |
 65%
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How many dihalogen derivatives of propane are there?

1. 1 2. 2
3. 3 4. 4
Subtopic:  Isomerism & Chirality |
 51%
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PCl5 reacts with propanone, to give:

1. gem dichloride

2. vic dichloride

3. propanal

4. propane chloride

Subtopic:  Chemical Properties |
 73%
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The correct match of column I (Reactions) with column II (Name of reactions) is:

Column I Column II
A. 1. Fittig reaction
B. 2. Wurtz-Fittig reaction
C. 3. Finkelstein reaction
D.  \(\begin{aligned}\small{C_{2}H_{5}Cl \ + \ NaI \ \xrightarrow[]{\textbf{dry acetone}} \\ \ C_{2}H_{5}I \ + \ NaCl} \end{aligned}\)  4. Sandmeyer reaction

Codes

A B C D
1. 2 1 4 3
2. 3 1 4 2
3. 1 4 3 2
4. 4 1 3 2
Subtopic:  Chemical Properties |
 91%
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Match the reactions given in Column I with the types of reactions given in Column II and mark the appropriate option.

Column I Column II
A.  
 
1. Nucleophilic
aromatic
substitution
reaction
B.  
2. Electrophilic
aromatic
substitution
C.  
3. Saytzeff
elimination
D
4. Electrophilic
addition

5. Nucleophilic
substitution
reaction

Codes

A B C D
1. 2 4 5 1
2. 3 1 5 2
3. 5 4 3 2
4. 4 5 3 2
Subtopic:  Chemical Properties |
 74%
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