The effect of branching on an alkane :

1. Increases its boiling point

2. Decreases its boiling point

3. Doesn’t change its boiling point

4. None of the above

Subtopic:  Aliphatic Hydrocarbon- Physical Properties |
 88%
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The product obtained on the addition of HBr to propene in the absence and presence of benzoyl peroxide are respectively

1. 1-Bromopropane, 2-Bromopropane

2. 2-Bromopropane, 1-Bromopropane

3. 1-Bromopropanol, 2-Bromopropanone

4. 2-Bromopropanone, 1-Bromopropanol

Subtopic:  Aliphatic Hydrocarbon -Nomenclature, Isomerism & Mechanism |
 83%
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Decreasing order of acidic behavior of benzene, n-hexane, and ethyne is -

1. Hexane > Ethyne > Benzene

2. Benzene > Hexane > Ethyne

3. Ethyne > Benzene > Hexane

4. Benzene > Ethyne > Hexene

Subtopic:  Alkanes, Alkenes and Alkynes - Chemical Properties |
 84%
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Incorrect statement towards reactivity of benzene is:

1. It undergoes electrophilic substitution reactions very easily
2. Nucleophiles are attracted by a benzene ring
3. Benzene is a planar molecule 
4. It has 12 sigma bonds

Subtopic:  Aromatic Hydrocarbons - Nomenclature, Isomerism & Huckel's Rule |
 69%
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Ethyne ? Benzene 

The reagent used in the above conversion is:

1. Cr2O3

2. Alc. KOH

3. Red hot Fe

4. NaNH2/liq.NH3

Subtopic:  Aromatic Hydrocarbons - Reactions & Mechanism |
 88%
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Out of the above alkenes, the ones that can give 2-methyl butane on hydrogenation are-

1. a, b 2. b, c
3. a, c 4. a, b, c
Subtopic:  Alkanes, Alkenes and Alkynes - Chemical Properties |
 75%
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The correct order of decreasing reactivity of the following compounds:

Chlorobenzene, 2,4-Dinitrochlorobenzene, and p-Nitrochlorobenzene

with an electrophile (E+)  is :

1. Chlorobenzene > p–Nitrochlorobenzene > 2,4-Dinitrochlorobenzene
2. p – Nitro chlorobenzene > 2, 4-Dinitrochlorobenzene > Chlorobenzene 
3. Chlorobenzene  > 2, 4-Dinitrochlorobenzene > p-Nitrochlorobenzene
4. 2, 4-Dinitrochlorobenzene > Chlorobenzene > p-Nitrochlorobenzene 

Subtopic:  Alkanes, Alkenes and Alkynes - Chemical Properties |
 68%
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The products of ozonolysis of 1,2-dimethyl benzene (o-xylene) are -

1. Methylglyoxal, 1, 2-dimethylglyoxal, and glyoxal

2. Methylglyoxal, 1, 3-dimethylglyoxal, and glyoxal

3. Methylglyoxal, 1, 4-dimethylglyoxal, and glyoxal

4. Methylglyoxal, 1, 5-dimethylglyoxal, and glyoxal

Subtopic:  Aromatic Hydrocarbons - Reactions & Mechanism |
 72%
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 Match the hydrocarbons in Column I with the boiling points given in Column II.

A. n-pentane 1. 282.5 K
B. iso-pentane 2. 309 K
C. neo-pentane 3. 301 K


Codes

Options:  A   B   C 
1. 2 3 1
2. 1 2 3
3. 2 1 3
4. 3 2 1
Subtopic:  Aliphatic Hydrocarbon- Physical Properties |
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Match the reactions given in Column I with the type of reaction given
in Column II and mark the appropriate option.

Column I Column II
A. CH2=CH2 + H2\(\xrightarrow[]{H^{+}}\)
CH3CH2OH
1. Hydrogenation
B. CH2=CH2 + H2 \(\xrightarrow[]{Pd}\)
CH3-CH3
2. Halogenation
C. CH2=CH2 + Cl2
Cl-CH2-CH2-Cl
3. Polymerisation
D. 3CH≡CH \(\xrightarrow[heat]{Cu \ tube}\)
C6H6
4. Hydration
5.  Condensation

Codes

Options:  A   B   C   D 
1.    2    3        4      1      
2. 1 2 3 5
3. 5 4 3 2
4. 4 1 2 3
Subtopic:  Alkanes, Alkenes and Alkynes - Chemical Properties |
 89%
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