The \(K_a\) values of formic acid and acetic acid are respectively $1.77\times {10}^{-4}$ and $1.75\times {10}^{-5}$. The ratio of the acid strength of 0.1 N acids is :

1. 0.1

2. 0.3

3. 3.178

4. 100

ZnS is not precipitated by passing H₂S in an acidic medium but CuS is precipitated. The reason for it is

1. ${\mathrm{K}}_{\mathrm{sp}}<mspace\; width="1em"></mspace>\mathrm{CuS}<<{\mathrm{K}}_{\mathrm{sp}}<mspace\; width="1em"></mspace>\mathrm{ZnS}$

2.$<mspace\; width="1em"></mspace>{\mathrm{K}}_{\mathrm{sp}}<mspace\; width="1em"></mspace>\mathrm{CuS}>>{\mathrm{K}}_{\mathrm{sp}}<mspace\; width="1em"></mspace>\mathrm{ZnS}$

3. ${\mathrm{K}}_{\mathrm{sp}}<mspace\; width="1em"></mspace>\mathrm{CuS}={\mathrm{K}}_{\mathrm{sp}}<mspace\; width="1em"></mspace>\mathrm{ZnS}$

4. None of these

Consider the following acids:

The correct order of strength is:
1. II>III>I>IV
2. IV>II>III>I
3. IV>III>II>I
4. III>II>IV>I

The hydrogen ion concentration is 0.2 M ethanoic acid $({\mathrm{K}}_{\mathrm{C}}=2\times {10}^{-5}<mspace\; width="1em"></mspace>\mathrm{mol}<mspace\; width="1em"></mspace>{\mathrm{dm}}^{-3})$ is approximately

1. ${10}^{-4}$

2. $2\times {10}^{-2}$

3. $2\times {10}^{-6}$

4. $2\times {10}^{-3}$

The pH of a solution made by mixing 50 mL of 0.01 M barium hydroxide solution with 50 mL of H₂O is

Find the molar solubility of Fe(OH)₃ in a buffer solution that 0.10 M in NH₄Cl and 0.10 M in NH₃. If ${\mathrm{K}}_{\mathrm{b}}<mspace\; width="1em"></mspace>\left({\mathrm{NH}}_3\right)=1.8\times {10}^{-5}$ and ${\mathrm{}}_{}$
\(\text K_{ \text {sp}} [ \text {Fe(OH)}_3] = 2.6 \times 10^{-39}\)

1. \(4 .458 \times 10^{-25}~ \mathrm{M} \)
2. \(3.458 \times 10^{-25}~ \mathrm{M} \)
3. \(2 .229 \times 10^{-24} ~\mathrm{M} \)
4. \(4.458 \times 10^{-22} ~\mathrm{M}\)

A base dissolved in water yields a solution with a hydroxyl ion concentration of \(0.05 \mathrm{~mol}~ \mathrm{litre}^{-1}\). The solution is:

Given that the ionization constant (\(K_a\)) of acetic acid \((\text{CH}_3\text{COOH})\) is \(1.7 \times 10^{-5}\) and the concentration of hydrogen ions (\(\text{H}^+ \)) is \(3.4 \times 10^{-4}\), what is the initial concentration of acetic acid (\(\text{CH}_3\text{COOH}\))?

1. \(3 . 4 \times \left(10\right)^{- 4}\)

2. \(3 . 4 \times \left(10\right)^{- 3}\)

3. \(6 . 8 \times \left(10\right)^{- 4}\)

4. \(6 . 8 \times \left(10\right)^{- 3}\)

At $25°\mathrm{C}$ the dissociation constant of a base, BOH is $1.0\times {10}^{-12}$, the concentration of hydroxyl ions 0.01 M aqueous solution of the base would become

1. $2.0\times {10}^{-6}<mspace\; width="1em"></mspace>\mathrm{mol}<mspace\; width="1em"></mspace>{\mathrm{L}}^{-1}$

2. $1.0\times {10}^{-5}<mspace\; width="1em"></mspace>\mathrm{mol}<mspace\; width="1em"></mspace>{\mathrm{L}}^{-1}$

3. $1.0\times {10}^{-6}<mspace\; width="1em"></mspace>\mathrm{mol}<mspace\; width="1em"></mspace>{\mathrm{L}}^{-1}$

4. $1.0\times {10}^{-7}<mspace\; width="1em"></mspace>\mathrm{mol}<mspace\; width="1em"></mspace>{\mathrm{L}}^{-1}$

The solubility product of AgI at $25°\mathrm{C}$ is $1.0\times {10}^{-16}<mspace\; width="1em"></mspace>{\mathrm{mol}}^2<mspace\; width="1em"></mspace>{\mathrm{L}}^{-2}$. The solubility of AgI in 10^-4 N solution of KI at $25°\mathrm{C}$ is :  (in mol L^-1)

1. $1.0\times {10}^{-10}$

2. $1.0\times {10}^{-8}$

3. $1.0\times {10}^{-16}$

4. $1.0\times {10}^{-12}$